3,5-dimethylpyrazolium fluorochromate(Vl)-catalysed oxidation of organic substrates by hydrogen peroxide under solvent-free conditions

被引：7
|
作者：
Chaudhuri, MK [1 ]
Dehury, SK
Hussain, S
Duarah, A
Gogoi, N
Kantam, ML
机构：
[1] Indian Inst Technol, Gauhati 781039, India
[2] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2005年 / 347卷 / 10期
关键词：
alcohols; catalytic oxidation; chromium; 3,5-dimethylpyrazolium fluorochromate(VI); hydrogen peroxide; solvent-free organic reactions;
D O I：
10.1002/adsc.200505116
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
3,5-Dimethylpyrazolium fluorochromate (VI), C5H8N2H[CrO3F], DmpzHFC, serves as an efficient catalyst for oxidation of primary, secondary and allylic alcohols to the corresponding carbonyl compounds using H2O2 at room temperature under solvent-free conditions. Oxidation of methyl phenyl sulfides and triphenylphosphine were also carried out successfully.
引用
收藏
页码：1349 / 1352
页数：4
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