Comparison of oxidation model predictions with gasification data of IG-110, IG-430 and NBG-25 nuclear graphite

A phenomenological oxidation kinetics model of graphite is presented and its results are compared with the reported experimental gasification data for nuclear graphite of IC-110, IG-430 and NBG-25. The model uses four elementary chemical kinetics reactions, employs Gaussian-like distributions of the specific activation energies for adsorption of oxygen and desorption of CO gas, and accounts for the changes in. the effective surface areas of free active sites and stable oxide complexes with weight loss. The distributions of the specific activation energies for adsorption and desorption, the values of the pre-exponential rate coefficients for the four elementary chemical reactions and the surface area of free active sites are obtained from the reported measurements using a multi-parameter optimization algorithm. At high temperatures, when gasification is diffusion limited, the model calculates the diffusion velocity of oxygen in the boundary layer using a semi-empirical correlation developed for air flows at Reynolds numbers ranging from 0.001 to 100. The model also accounts for the changes in the external surface area, the oxygen pressure in the bulk gas mixture and the effective diffusion coefficient in the boundary layer with weight loss. The model results of the total gasification rate and weight loss with time in the experiments agree well with the reported measurements for the three types of nuclear graphite investigated, at temperatures from 723 to 1226 K and weight loss fractions up to similar to 0.86. (C) 2011 Elsevier B.V. All rights reserved.