Homoatomic Polyanions of the Early p-Block Elements

被引：6

作者：

Goicoechea, Jose M. ^{[1
]}

机构：

[1] Univ Oxford, Dept Chem, Chem Res Lab, 12 Mansfield Rd, Oxford OX1 3TA, England

来源：

CLUSTERS - CONTEMPORARY INSIGHT IN STRUCTURE AND BONDING | 2017年 / 174卷

关键词：

Clusters; Pnictogens; Polyanions; Tetrels; Triels; Zintl ions; STABLE HOMOPOLYATOMIC ANIONS; LOW-TEMPERATURE MODIFICATION; LOW-DIMENSIONAL ARRANGEMENT; METALLIC ZINTL PHASE; CRYSTALLINE COMPOUNDS <NA4.7EN>SN9; ELECTRON LOCALIZATION FUNCTION; ALKALIMETALLE ZU HALBMETALLEN; 9-ATOM GERMANIUM CLUSTERS; POST TRANSITION-ELEMENTS; LIQUID-AMMONIA SOLUTIONS;

D O I：

10.1007/430_2015_5003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This article reviews the chemistry of homoatomic polyanions of the early p-block elements (groups 13-15). The focus is on species that have been structurally authenticated in solid-state compounds and/or isolated from solution. The structures, bonding, electronic properties, and formation pathways of these homoatomic species are described in detail.

引用

页码：63 / 97

页数：35

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