A New 3D 4d-4f La-Ag Coordination Polymer Constructed by Interesting [Ag2]n and Flat [La2(IN)6(CH3COO)]n Layers

被引：4

作者：

Huang, Lian ^{[1
]}

Mei, Hua ^{[1
]}

Chen, Lei ^{[1
]}

Xu, Yan ^{[1
,2
]}

机构：

[1] Nanjing Univ Technol, Coll Chem & Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Peoples R China

[2] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2012年 / 638卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Lanthanide cluster; 4d-4f; Coordination polymer; Crystal structure; Lanthanum; Silver; PHOTOLUMINESCENT PROPERTIES; CRYSTAL-STRUCTURES; COMPLEXES; LN; LIGANDS; LUMINESCENCE; FRAMEWORKS; SILVER(I); EU; SUBUNITS;

D O I：

10.1002/zaac.201100544

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

One new 3D La-Ag coordination compound formulated as [La2Ag3(IN)6(OAC)(H2O)3][NO3]2 center dot 2H2O (1) (HIN = isonicotinic acid; HOAC = acetic acid) was synthesized. The structure represents an interesting 3D open framework that is built upon 2D lanthanide layers and [Ag(IN)2]+ linkers. The triple helical [La(IN)2(H2O)]n chain and zigzag [LaIN(OAC)]n chain are found in the 2D La-IN layers. Channels are also found in the framework of 1, owing to shape-controlled synthesis templated by the free NO3 ions and water molecules.

引用

收藏

页码：996 / 1000

页数：5

相关论文

共 28 条

[1] Single-Crystal-to-Single-Crystal Transformation in a One-Dimensional Ag-Eu Helical System [J].

Cai, Yue-Peng ;

Zhou, Xiu-Xia ;

Zhou, Zheng-Yuan ;

Zhu, Shi-Zheng ;

Thallapally, Praveen K. ;

Liu, Jun .

INORGANIC CHEMISTRY, 2009, 48 (14) :6341-6343

[2] Metal-directed assembly of two 2-D 4d-4f coordination polymers based on elliptical triple-deck cylinders hinged by meso-double helical chains [J].

Cai, Yue-Peng ;

Yu, Qiong-Yan ;

Zhou, Zheng-Yuan ;

Hu, Zuo-Jun ;

Fang, Hua-Cai ;

Wang, Ning ;

Zhan, Qing-Guang ;

Chen, Li ;

Su, Cheng-Yong .

CRYSTENGCOMM, 2009, 11 (06) :1006-1013

[3] Mono-, di-, and trinuclear luminescent silver(I) and gold(I) N-heterocyclic carbene complexes derived from the picolyl-substituted methylimidazolium salt: 1-methyl-3-(2-pyridinylmethyl)-1H-imidazolium tetrafluoroborate [J].

Catalano, VJ ;

Moore, AL .

INORGANIC CHEMISTRY, 2005, 44 (19) :6558-6566

[4] Lanthanide-transition-metal sandwich framework comprising {Cu3} cluster pillars and layered networks of {Er36}) wheels [J].

Cheng, JW ;

Zhang, J ;

Zheng, ST ;

Zhang, MB ;

Yang, GY .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (01) :73-77

[5] Self-assembly of 3-D 4d-4f coordination frameworks based on 1-D inorganic heterometallic chains and linear organic linkers [J].

Gu, Xiaojun ;

Xue, Dongfeng .

CRYSTENGCOMM, 2007, 9 (06) :471-477

[6] Spontaneously resolved homochiral 3D lanthanide-silver heterometallic coordination framework with extended helical Ln-O-Ag subunits [J].

Gu, Xiaojun ;

Xue, Dongfeng .

INORGANIC CHEMISTRY, 2006, 45 (23) :9257-9261

[7] Selected controlled synthesis of three-dimensional 4d-4f heterometallic coordination frameworks by lanthanide carboxylate subunits and silver centers [J].

Gu, Xiaojun ;

Xue, Dongfeng .

CRYSTAL GROWTH & DESIGN, 2006, 6 (11) :2551-2557

[8] Synthesis, characterization and luminescence of two unusual 4d-4f Ln-Ag coordination compounds [J].

Han, Lijie ;

Zhou, Wanli ;

Yang, Yanhong ;

Xu, Yan .

INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (05) :385-387

[9] Reparameterized Herschbach-Laurie empirical relationships between metal-metal distances and force constants applied to homonuclear bi- and polynuclear complexes (M=Cr, Mo, Rh, Pd, Ag, W, Re, Ir, Pt, Au, Hg) [J].

Harvey, PD .

COORDINATION CHEMISTRY REVIEWS, 1996, 153 :175-198

[10] Hexanuclear 4d-4f complexes [Ln2Ag4(ina)8(H2O)10][NO3]2 • 4H2O (Ln = Sm, Eu, Dy):: Syntheses, structures and photolumine scent properties [J].

He, Yong-Ke ;

Han, Zheng-Bo .

INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (12) :1523-1526