Aqueous-Phase Transformation of Glucose into Hydroxymethylfurfural and Levulinic Acid by Combining Homogeneous and Heterogeneous Catalysis

被引:53
作者
Garces, Diego [1 ]
Faba, Laura [1 ]
Diaz, Eva [1 ]
Ordonez, Salvador [1 ]
机构
[1] Univ Oviedo, Dept Chem & Environm Engn, C Julian Claveria S-N, E-33006 Oviedo, Asturias, Spain
关键词
biomass; bio-platform molecules; biorefinery; kinetics; zeolites; 5-HYDROXYMETHYLFURFURAL HMF; HYDROCHLORIC-ACID; FORMIC ACIDS; D-FRUCTOSE; DEHYDRATION; CONVERSION; HYDROLYSIS; CELLULOSE; BIOMASS; DECOMPOSITION;
D O I
10.1002/cssc.201802315
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Homogeneous (HCl) and heterogeneous catalysts (various zeolites) were combined to enhance the upgrading of glucose into two different platform molecules: 5-hydroxymethylfurfural (HMF) and levulinic acid (LA). beta-Zeolite was the most active material for the glucose isomerization to fructose, improving also the activity of HCl for the subsequent steps. Reaction time, temperature, and pH were then modified, identifying 140 degrees C, 200 ppm of HCl, and 5 h as the optimum conditions for HMF formation (41 % selectivity; 0.06 mol L-1) and 140 degrees C, 400 ppm of HCl, and 24 h for LA formation (34 % selectivity; 0.12 mol L-1). This new approach is also relevant because of significant changes to the mechanism for humins formation. All results are successfully fitted to a kinetic model simultaneously considering both catalytic mechanisms.
引用
收藏
页码:924 / 934
页数:11
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