Tuning graphene properties by a multi-step thermal reduction process

被引:19
作者
Alvarez, Patricia [1 ]
Blanco, Clara [1 ]
Santamaria, Ricardo [1 ]
Blanco, Patricia [1 ]
Gonzalez, Zoraida [1 ]
Fernandez-Garcia, Laura [1 ]
Sierra, Uriel [1 ]
Granda, Marcos [1 ]
Paez, Antonio [2 ]
Menendez, Rosa [1 ]
机构
[1] CSIC, Inst Nacl Carbon, INCAR, E-33080 Oviedo, Spain
[2] REPSOL, Ctr Technol, Madrid 28935, Spain
关键词
GRAPHITE OXIDE; SHEETS;
D O I
10.1016/j.carbon.2015.04.022
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A multi-step thermal reduction process to produce graphene from graphite oxide was developed to optimize the degree of reduction, its BET surface area and its suitability as electrode in electrochemical energy storage devices. The procedure combines an initial flash pyrolysis to a temperature below 460 degrees C and a subsequent ramp-heating treatment up to the selected final temperature. With this methodology, the morphology of the graphene materials obtained, which has a great influence in their behavior as electrodes, is controlled. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:160 / 163
页数:4
相关论文
共 11 条
  • [1] Acik M., 2013, Journal of Materials Science Research, V2, P101
  • [2] Trends in green reduction of graphene oxides, issues and challenges: A review
    Agharkar, Mahesh
    Kochrekar, Sachin
    Hidouri, Slah
    Azeez, Musibau A.
    [J]. MATERIALS RESEARCH BULLETIN, 2014, 59 : 323 - 328
  • [3] Critical temperatures in the synthesis of graphene-like materials by thermal exfoliation-reduction of graphite oxide
    Botas, Cristina
    Alvarez, Patricia
    Blanco, Clara
    Santamaria, Ricardo
    Granda, Marcos
    Dolores Gutierrez, M.
    Rodriguez-Reinoso, Francisco
    Menendez, Rosa
    [J]. CARBON, 2013, 52 : 476 - 485
  • [4] The effect of the parent graphite on the structure of graphene oxide
    Botas, Cristina
    Alvarez, Patricia
    Blanco, Clara
    Santamaria, Ricardo
    Granda, Marcos
    Ares, Pablo
    Rodriguez-Reinoso, Francisco
    Menendez, Rosa
    [J]. CARBON, 2012, 50 (01) : 275 - 282
  • [5] The chemistry of graphene oxide
    Dreyer, Daniel R.
    Park, Sungjin
    Bielawski, Christopher W.
    Ruoff, Rodney S.
    [J]. CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) : 228 - 240
  • [6] From Conception to Realization: An Historial Account of Graphene and Some Perspectives for Its Future
    Dreyer, Daniel R.
    Ruoff, Rodney S.
    Bielawski, Christopher W.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (49) : 9336 - 9344
  • [7] Thermally reduced graphite and graphene oxides in VRFBs
    Gonzalez, Zoraida
    Botas, Cristina
    Blanco, Clara
    Santamaria, Ricardo
    Granda, Marcos
    Alvarez, Patricia
    Menendez, Rosa
    [J]. NANO ENERGY, 2013, 2 (06) : 1322 - 1328
  • [8] Single sheet functionalized graphene by oxidation and thermal expansion of graphite
    McAllister, Michael J.
    Li, Je-Luen
    Adamson, Douglas H.
    Schniepp, Hannes C.
    Abdala, Ahmed A.
    Liu, Jun
    Herrera-Alonso, Margarita
    Milius, David L.
    Car, Roberto
    Prud'homme, Robert K.
    Aksay, Ilhan A.
    [J]. CHEMISTRY OF MATERIALS, 2007, 19 (18) : 4396 - 4404
  • [9] Latex and two-roll mill processing of thermally-exfoliated graphite oxide/natural rubber nanocomposites
    Potts, Jeffrey R.
    Shankar, Om
    Murali, Shanthi
    Du, Ling
    Ruoff, Rodney S.
    [J]. COMPOSITES SCIENCE AND TECHNOLOGY, 2013, 74 : 166 - 172
  • [10] Functionalized single graphene sheets derived from splitting graphite oxide
    Schniepp, HC
    Li, JL
    McAllister, MJ
    Sai, H
    Herrera-Alonso, M
    Adamson, DH
    Prud'homme, RK
    Car, R
    Saville, DA
    Aksay, IA
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (17) : 8535 - 8539