Spectroscopic, thermal and structural studies of a new mercury(II) one-dimensional coordination polymer, [Hg(3-bpo)2(SCN)2], 3-bpo=2,5-bis(3-pyridyl)-1,3,4-oxadiazole

被引：3
作者：
Fard-Jahromi, Mohammad Jafar Soltanian [2 ]
Morsali, Ali [1 ]
Zeller, Matthias [3 ]
机构：
[1] Tarbiat Modares Univ, Dept Chem, Fac Sci, Tehran, Iran
[2] Islamic Azad Univ, Fac Basic Sci, Dept Chem Sci & Res Campus, Tehran, Iran
[3] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 14期
关键词：
mercury(II); 2,5-bis(3-pyridyl)-1,3,4-oxadiazole; crystal structure; coordination polymer;
D O I：
10.1080/00958970801901501
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new mercury(II)-organic polymeric complex generated from 2,5-bis(3-pyridyl)-1,3,4-oxadiazole (3-bpo) as an angular dipyridyl derivative ligand, [Hg(3-bpo)(2)(SCN)(2)], was prepared from reactions of ligand 3-bpo with mercury(II) thiocyanate. The compound was characterized by elemental analysis, IR-, H-1 NMR-, C-13 NMR-spectroscopy and structurally determined by X-ray single crystal diffraction. The thermal stability of [Hg(3-bpo)(2)(SCN)(2)] was studied by thermal gravimetric (TG) and differential thermal analyses (DTA).
引用
收藏
页码：2227 / 2233
页数：7
相关论文
共 50 条
  • [41] New mixed-anion mercury(II) complex, spectroscopic, thermal and structural studies of [Hg(bipy)2(CH3COO)]2(SO4)•0.5NaCl
    Ramazani, Ali
    Mahmoudi, Ghodrat
    Dolatyari, Leila
    Morsali, Ali
    Hu, Mao-Lin
    JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (19) : 2115 - 2120
  • [42] Copper(II) coordination chain complex with the 2,5-bis(2-pyridyl)-1,3,4-thiadiazole ligand and an asymmetric μ2-1,1-azido double bridged: Synthesis, crystal structure and magnetic properties
    Laachir, Abdelhakim
    Guesmi, Salaheddine
    Saadi, Mohamed
    El Ammari, Lahcen
    Mentre, Olivier
    Vezin, Herve
    Colis, Silviu
    Bentiss, Fouad
    JOURNAL OF MOLECULAR STRUCTURE, 2016, 1123 : 400 - 406
  • [43] Cobalt(II) coordination complex with 2,5-bis(pyridine-2-yl)-1,3,4-thiadiazole and thiocyanate as co-ligand: Synthesis, crystal structure, Hirshfeld surface analysis, spectroscopic, thermal and magnetic properties
    Laachir, Abdelhakim
    Rhoufal, Ferdaousse
    Guesmi, Salaheddine
    Ketatni, El Mostafa
    Jouffret, Laurent
    Hlil, El Kebir
    Sergent, Nicolas
    Obbade, Said
    Bentiss, Fouad
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1208
  • [44] Synthesis and characterizations of a novel dia-type Ag-BPT coordination polymer with tetranuclear motifs as jointing points (BPT=3,5-bis(3-pyridyl)-1,2,4-triazole)
    Zhai, Quan-Guo
    Hu, Man-Cheng
    Wang, Yan
    Ji, Wen-Juan
    Li, Shu-Ni
    Jiang, Yu-Cheng
    INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (04) : 286 - 289
  • [45] Benzenedicarboxylate-modulated zinc(II)-3,5-bis(3-pyridyl)-1H-1,2,4-triazole frameworks: syntheses, structures and luminescent properties
    Li, Bing
    Chen, Sanping
    Xie, Gang
    Yang, Qi
    Gao, Shengli
    STRUCTURAL CHEMISTRY, 2012, 23 (02) : 417 - 423
  • [46] Benzenedicarboxylate-modulated zinc(II)-3,5-bis(3-pyridyl)-1H-1,2,4-triazole frameworks: syntheses, structures and luminescent properties
    Bing Li
    Sanping Chen
    Gang Xie
    Qi Yang
    Shengli Gao
    Structural Chemistry, 2012, 23 : 417 - 423
  • [47] One-dimensional holodirected lead(II) coordination polymer, [Pb(μ2-TPPZ)(NO3)(ClO4)]n (TPPZ=2,3,5,6-tetra(2-pyridyl)pyrazine)
    Morsali, A
    Ramazani, A
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (10): : 1759 - 1760
  • [48] Synthesis, Structural Characterization and Thermal Stability of A One-Dimensional Chain-like Coordination Polymer, [Fe(bpno)2(NCS)3]
    Chiu, Hsiu-Hui
    Shen, Mei-Chi
    Wang, Chih-Chieh
    Lee, Gene-Hsiang
    Sheu, Hwo-Shuenn
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2013, 60 (07) : 719 - 724
  • [49] Four coordination polymers derived from 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole and copper sulfate
    Liu, Kui
    Zhu, Xia
    Wang, Ju
    Li, Baolong
    Zhang, Yong
    INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (08) : 976 - 980
  • [50] Synthesis and Crystal Structure of a Novel Manganese Coordination Polymer: 2,5-Bis(4-pyridyl)-3,4-diaza-2,4-hexadiene
    CHEN Man-Sheng DENG Yi-Fang ZHANG Chun-Hua KUANG Dai-Zhi② FENG Yong-Lan PENG Yun-Lin (Department of Chemistry and Materials Science
    Chinese Journal of Structural Chemistry, 2007, (02) : 219 - 223
12345