Spectroscopic, thermal and structural studies of a new mercury(II) one-dimensional coordination polymer, [Hg(3-bpo)2(SCN)2], 3-bpo=2,5-bis(3-pyridyl)-1,3,4-oxadiazole

被引：3
|
作者：
Fard-Jahromi, Mohammad Jafar Soltanian [2 ]
Morsali, Ali [1 ]
Zeller, Matthias [3 ]
机构：
[1] Tarbiat Modares Univ, Dept Chem, Fac Sci, Tehran, Iran
[2] Islamic Azad Univ, Fac Basic Sci, Dept Chem Sci & Res Campus, Tehran, Iran
[3] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 14期
关键词：
mercury(II); 2,5-bis(3-pyridyl)-1,3,4-oxadiazole; crystal structure; coordination polymer;
D O I：
10.1080/00958970801901501
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new mercury(II)-organic polymeric complex generated from 2,5-bis(3-pyridyl)-1,3,4-oxadiazole (3-bpo) as an angular dipyridyl derivative ligand, [Hg(3-bpo)(2)(SCN)(2)], was prepared from reactions of ligand 3-bpo with mercury(II) thiocyanate. The compound was characterized by elemental analysis, IR-, H-1 NMR-, C-13 NMR-spectroscopy and structurally determined by X-ray single crystal diffraction. The thermal stability of [Hg(3-bpo)(2)(SCN)(2)] was studied by thermal gravimetric (TG) and differential thermal analyses (DTA).
引用
收藏
页码：2227 / 2233
页数：7
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