n-Bu4NI/TBHP-catalyzed C-N bond formation via cross-dehydrogenative coupling of 1H-1,2,4-triazoles (N-H) and methylarenes (Csp3-H)

被引：13
作者：
Abebe, Habtamu
Vidavalur, Siddaiah [1 ]
Battula, Venkateswara Rao
机构：
[1] Andhra Univ, Coll Sci & Technol, Dept Organ Chem, Visakhapatnam, Andhra Pradesh, India
来源：
RSC ADVANCES | 2016年 / 6卷 / 85期
关键词：
METAL-FREE; OXIDATIVE ESTERIFICATION; MEDIATED CARBONYLATION; EFFICIENT SYNTHESIS; DUAL AROMATASE; 1,2,4-TRIAZOLES; ETHERS; AZOLES; 1,2,4-OXADIAZOLES; ALKYLBENZENES;
D O I：
10.1039/c6ra18968g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient n-Bu4NI/TBHP-catalyzed protocol for C-N bond formation via cross-dehydrogenative coupling of 1H-1,2,4-triazoles (N-H) and methylarenes (C-sp3-H) has been developed under metal free conditions. A series of methylarenes and 1H-1,2,4-triazoles are tolerated in this method and gave the corresponding 1-benzyl-1,2,4-triazoles in moderate to good yields.
引用
收藏
页码：82289 / 82293
页数：5
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