We report measurements of photostimulated electron emission (PSE) from single-crystalline aluminum (99.995%) and high-purity polycrystalline aluminum (> 99.9%) during uniaxial tensile deformation. Photoelectron intensities are sensitive to changes in surface morphology accompanying deformation, including slip line and slip band formation. In the single crystalline material, the PSE intensity increases linearly with strain. In the polycrystalline material, the PSE intensity increases exponentially with strain. In both materials, time-resolved PSE measurements show step-like increases in intensity consistent with the heterogeneous nucleation and growth of slip bands during tensile deformation. In this sense, we have "observed" dislocation motion by this technique. Slip bands on the surfaces of deformed samples were subsequently imaged by atomic-force microscopy (AFM). Photoelectron measurements can provide reliable, quantitative information for dislocation dynamics. (c) 2005 Elsevier B.V. All rights reserved.