In situ preparation, structure, photophysical properties of a novel zinc complex

被引：0

作者：

Chen, Yang-Qing ^{[1
]}

Peng, Hai-Qi ^{[1
]}

Ji, Qiong ^{[1
]}

Wang, Xuan-Xuan ^{[1
]}

Wei, Lijun ^{[1
]}

Zhong, Qiu-Yue ^{[1
]}

Chen, Wen-Tong ^{[1
,2
,3
]}

机构：

[1] Jinggangshan Univ, Inst Appl Chem, Sch Chem & Chem Engn,Jiangxi Prov Key Lab Coordin, Jian Key Lab Photoelect Crystal Mat & Device,Hum, Jian 343009, Jiangxi, Peoples R China

[2] Wuyi Univ, Dept Ecol & Resources Engn, Fujian Key Lab Ecoind Green Technol, Wuyishan, Fujian, Peoples R China

[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou, Fujian, Peoples R China

来源：

INORGANIC AND NANO-METAL CHEMISTRY | 2024年 / 54卷 / 05期

关键词：

CIE; in situ reaction; hydrothermal; photoluminescence; zinc; METAL-ORGANIC FRAMEWORKS; HIGHLY DENSE PACKING; COORDINATION POLYMERS; TEMPERATURE; CATALYST; LIGANDS;

D O I：

10.1080/24701556.2021.2025095

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel zinc complex [ZnI3(N-benzyl-4,4'-bipy)]center dot 2MeOH center dot H3O (1) (bipy = bipyridine; MeOH = methanol) is synthesized and characterized. This complex is characterized by an isolated structure. The photoluminescence spectra using solid state samples unveiled that this complex can show a green photoluminescence emission. As revealed by the TDDFT (time-dependent density functional theory) calculation results, the photoluminescence emission should rise from an intraligand charge transfer (ILCT). The complex possesses CIE (Commission Internationale de I'eclairage) chromaticity coordinates of 0.1305 and 0.3855. A solid-state UV-Visible diffuse reflectance spectrum shows that this complex has a narrow optical band gap of 1.87 eV.

引用

页码：467 / 473

页数：7

共 44 条

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