Clean Procedure for the Synthesis of -Aminophosphonates Catalyzed by Choline-Based Ionic Liquid

被引：9

作者：

Peng, Huan ^{[1
]}

Sun, Siyu ^{[1
]}

Hu, Yulin ^{[1
]}

Xing, Rong ^{[1
]}

Fang, Dong ^{[1
,2
]}

机构：

[1] Yancheng Normal Univ, Sch Chem & Chem Engn, Yancheng 224002, Peoples R China

[2] Jiangsu Prov Key Lab Coast Wetland Bioresources &, Yancheng 224002, Peoples R China

来源：

HETEROATOM CHEMISTRY | 2015年 / 26卷 / 03期

关键词：

ONE-POT SYNTHESIS; KABACHNIK-FIELDS REACTION; ALPHA-AMINOPHOSPHONATES; EFFICIENT CATALYST; 3-COMPONENT SYNTHESIS; AMINO PHOSPHONATES; ACID; CONVENIENT; WATER; HETEROPOLYANION;

D O I：

10.1002/hc.21251

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A sulfated choline-based ionic liquid [Ch-OSO3H] was prepared and used as a novel catalyst for the synthesis of -aminophosphonates via a one-pot three-component reaction with aldehydes, amines, and triethyl phosphite/diethyl phosphite at room temperature under solvent-free conditions or in aqueous media. The reaction was completed in short times and products could be simply separated from the reaction mixture in good to excellent yields. The catalyst could be recycled and reused for several times without noticeably reducing catalytic activity. (C) 2014 Wiley Periodicals, Inc.

引用

页码：215 / 223

页数：9

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