Milestones in microwave-assisted organophosphorus chemistry

被引：5
作者：
Keglevich, Gyoergy [1 ]
Kiss, Nora Z. [1 ]
Balint, Erika [1 ]
Bagi, Peter [1 ]
Gruen, Alajos [1 ]
Kovacs, Tamara [1 ]
Henyecz, Reka [1 ]
Abranyi-Balogh, Peter [1 ]
机构：
[1] Budapest Univ Technol & Econ, Dept Organ Chem & Technol, H-1521 Budapest, Hungary
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2016年 / 191卷 / 11-12期
关键词：
Microwave; organophosphorus chemistry; P-heterocycles; reactions; catalyst systems; KABACHNIK-FIELDS REACTION; SOLVENT-FREE CONDITIONS; P-LIGAND-FREE; ALPHA-AMINOPHOSPHINE OXIDES; CHELATE PLATINUM COMPLEXES; PHOSPHINIC ACIDS; HIRAO REACTION; EFFICIENT SYNTHESIS; HYDROXY-METHYLENEBISPHOSPHONATES; DIRECT ESTERIFICATION;
D O I：
10.1080/10426507.2016.1211657
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The microwave (MW) technique become an important tool in organophosphorus chemistry. On the one hand, otherwise reluctant reactions, such as the Diels-Alder cycloadditions, inverse Wittig-type reactions, esterification of P-acids, alcoholysis of P-esters, may be promoted on the effect of MW, while on the other hand, catalysts may be omitted, or catalyst systems may be simplified on MW irradiation. This later group includes the Kabachnik-Fields and the Pudovik reactions, deoxygenation, as well as the Hirao- and the Arbuzov reactions. [GRAPHICS] .
引用
收藏
页码：1416 / 1420
页数：5
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