Reactions of the triosmium cluster Os3(μ-H)(μ-OH)(CO)10 with naphthols

被引：8

作者：

Lum, MW ^{[1
]}

Leong, WK ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 119260, Singapore

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 687卷 / 01期

关键词：

osmium; clusters; naphthol;

D O I：

10.1016/j.jorganchem.2003.08.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the cluster Os-3(mu-H)(mu-OH)(CO)(10) (1) with 1-naphthol afforded the isomeric clusters 2a and 3a with the formulae OS3(mu-H)(2)(mu(3)-1-OC10H6)(CO)(9). A similar reaction with 2-naphthol, however, gave Os-3(mu-H)(mu-2-OC10H7)C)(10), 4b, and the analogue of 2a. These clusters have been structurally characterised to confirm the mode of anchoring of the naphthols. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：203 / 208

页数：6

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