Synthesis, Structural Characterization and Metal Inclusion Properties of 18-, 20-and 22-Membered Oxaazacyclophanes and Oxaazacalix[4]arene Analogues: Macrocyclic Amine and Schiff Base Receptors with Variable NxOy Donor Sets

被引：15

作者：

Moreno-Corral, Ramon ^{[1
]}

Hoepfl, Herbert ^{[2
]}

Machi-Lara, Lorena ^{[1
]}

Lara, Karen O. ^{[1
]}

机构：

[1] Univ Sonora, Dept Invest Polimeros & Mat, Hermosillo 83000, Sonora, Mexico

[2] Univ Autonoma Estado Morelos, Ctr Invest Quim, Cuernavaca 62209, Morelos, Mexico

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 2011卷 / 11期

关键词：

Schiff bases; Macrocycles; Cyclophanes; Calixarenes; Metal complexes; COMPLEXES; COORDINATION; LUMINESCENT; POLYAMINES; LIGANDS; CU(II); OXYGEN; CROWN; IONS;

D O I：

10.1002/ejoc.201001312

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of oxaazacyclophanes and oxaazacalix[4]arene analogues with 18-, 20- and 22-membered rings have been synthesized from diamine and dialdehyde building blocks and structurally characterized by spectroscopic methods. One diamine precursor and four macrocycles have additionally been analysed by single-crystal X-ray diffraction. Two of the oxaazacalix[4]arene analogues were employed for metal ion complexation studies based on UV/Vis absorption spectroscopy, showing both compounds to be able to form complexes with Cu2(+) and Zn2(+).

引用

页码：2148 / 2162

页数：15

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