Selective photosensitized oxidation and its catalytic regulation of monoterpene with molecular oxygen in different reaction media

被引：11

作者：

You, Kuiyi ^{[1
]}

Yin, Dulin ^{[2
]}

Mao, Liqiu ^{[2
]}

Liu, Pingle ^{[1
]}

Luo, He'an ^{[1
]}

机构：

[1] Xiangtan Univ, Coll Chem Engn, Xiangtan 411105, Peoples R China

[2] Hunan Normal Univ, Inst Fine Catalysis & Synth, Minist Educ, Key Lab Chem Biol & Tradit Chinese Med Res, Changsha 410081, Hunan, Peoples R China

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2011年 / 217卷 / 2-3期

基金：

中国国家自然科学基金;

关键词：

Photosensitized oxidation; Catalytic regulation; Monoterpene; Molecular oxygen; SINGLET OXYGEN; RED-LIGHT; ZEOLITES; ALKENES; PHOTOOXIDATION; CYCLOHEXENE; COMPLEXES; IRON(III); OLEFINS; STATE;

D O I：

10.1016/j.jphotochem.2010.10.026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The photo-catalytic oxidation of a-pinene, beta-pinene and limonene with molecular oxygen sensitized by tetrachlorotetraiodo-fluorescein sodium salt (RB) has been studied in different reaction media under green light irradiation. Simple and efficient photosensitized oxidation equipment was employed successfully to improve the efficiency of the photosensitized reaction. The results indicate that the photosensitized oxidation products can be directly obtained without after-treatment by reductive reagent. Furthermore, it was found that the product distributions are remarkably affected by reaction media, and that N,N-dimethylformamide (DMF) can regulate the selectivity to products. In particular, the good selectivity (85%) to the main product (myrtenal) and the excellent conversion (99%) were obtained in the absence of any other catalysts when DMF was used as reaction solvent in the photosensitized oxidation of beta-pinene. Moreover, the possible photosensitized oxidation reaction mechanism in different media was suggested in the present work. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：321 / 325

页数：5

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