TiO2/graphene porous composite and its photocatalytic degradation of methylene blue

被引:131
作者
Yang, Yongfang [1 ]
Xu, Lidong [1 ]
Wang, Hefang [1 ]
Wang, Wenjie [1 ]
Zhang, Lixin [1 ]
机构
[1] Hebei Univ Technol, Sch Chem Engn & Technol, Tianjin 300130, Peoples R China
基金
中国国家自然科学基金;
关键词
Graphene; TiO2; Porous; Methylene blue; Photocatalytic; TIO2; PHOTOCATALYSIS; HIGH-PERFORMANCE; GRAPHENE; REMOVAL; SURFACE;
D O I
10.1016/j.matdes.2016.06.104
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
TiO2/graphene porous composites with reduced graphene oxide (rGO) as its inner surface were prepared based on graphene microspheres colloidal crystals template. The structure and morphology of TiO2/graphene porous composites were characterized by Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and scanning electron microscopy (SEM). With rGO sheets as the interface of the porous TiO2/graphene, the composites exhibited high light absorbing capacity, high adsorption ability for methylene blue (MB) and fast charge transportation and separation ability. TiO2/graphene porous composites showed superior activity in the degradation of MB under visible light. The rate constant of TiO2/graphene porous composite was 0.0208 min(-1), which was almost 6.5 times higher than P25 under the visibl-light-driven radiation. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:632 / 639
页数:8
相关论文
共 40 条
[1]   Visible light responsive titanium dioxide-cyclodextrin-fullerene composite with reduced charge recombination and enhanced photocatalytic activity [J].
Ali, Mohamed Mukthar ;
Sandhya, K. Y. .
CARBON, 2014, 70 :249-257
[2]   Semiconductor-based Photocatalytic Hydrogen Generation [J].
Chen, Xiaobo ;
Shen, Shaohua ;
Guo, Liejin ;
Mao, Samuel S. .
CHEMICAL REVIEWS, 2010, 110 (11) :6503-6570
[3]   Preparation of graphene film decorated TiO2 nano-tube array photoelectrode and its enhanced visible light photocatalytic mechanism [J].
Cheng, Xiuwen ;
Liu, Huiling ;
Chen, Qinghua ;
Li, Junjing ;
Wang, Pu .
CARBON, 2014, 66 :450-458
[4]   Hierarchically Ordered Macro-Mesoporous TiO2-Graphene Composite Films: Improved Mass Transfer, Reduced Charge Recombination, and Their Enhanced Photocatalytic Activities [J].
Du, Jiang ;
Lai, Xiaoyong ;
Yang, Nailiang ;
Zhai, Jin ;
Kisailus, David ;
Su, Fabing ;
Wang, Dan ;
Jiang, Lei .
ACS NANO, 2011, 5 (01) :590-596
[5]  
Fujishima A., 2000, J PHOTOCH PHOTOBIO C, V1, P1, DOI [10.1016/S1389-5567(00)00002-2, DOI 10.1016/S1389-5567(00)00002-2]
[6]   TiO2 photocatalysis and related surface phenomena [J].
Fujishima, Akira ;
Zhang, Xintong ;
Tryk, Donald A. .
SURFACE SCIENCE REPORTS, 2008, 63 (12) :515-582
[7]   Enhanced photocatalytic activities of three-dimensional graphene-based aerogel embedding TiO2 nanoparticles and loading MoS2 nanosheets as Co-catalyst [J].
Han, Weijia ;
Zang, Chen ;
Huang, Zongyu ;
Zhang, Han ;
Ren, Long ;
Qi, Xiang ;
Zhong, Jianxin .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (34) :19502-19512
[8]   ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS [J].
HOFFMANN, MR ;
MARTIN, ST ;
CHOI, WY ;
BAHNEMANN, DW .
CHEMICAL REVIEWS, 1995, 95 (01) :69-96
[9]   P25-graphene hydrogels: Room-temperature synthesis and application for removal of methylene blue from aqueous solution [J].
Hou, Chengyi ;
Zhang, Qinghong ;
Li, Yaogang ;
Wang, Hongzhi .
JOURNAL OF HAZARDOUS MATERIALS, 2012, 205 :229-235
[10]   Photocatalytic reactions involving radical chain reactions using microelectrodes [J].
Ikeda, K ;
Sakai, H ;
Baba, R ;
Hashimoto, K ;
Fujishima, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (14) :2617-2620