High-performance flexible electrode based on electrodeposition of polypyrrole/MnO2 on carbon cloth for supercapacitors

被引:86
作者
Fan, Xingye [1 ]
Wang, Xiaolei [1 ]
Li, Ge [1 ]
Yu, Aiping [1 ]
Chen, Zhongwei [1 ]
机构
[1] Univ Waterloo, Dept Chem Engn, Waterloo Inst Nanotechnol, 200 Univ Ave West, Waterloo, ON N2L 3G1, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
Sueprcapacitors; Flexible electrodes; High capacitance; High rate capability; Manganese diodes; Polypyrrole; GRAPHENE; MNO2; NANOSTRUCTURES; CAPACITANCE; COMPOSITE; NANOCRYSTALS; FABRICATION;
D O I
10.1016/j.jpowsour.2016.05.047
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A highly flexible electrodes based on electrodeposited MnO2 and polypyrrole composite on carbon cloth is designed and developed by a facile in-situ electrodeposition technique. Such flexible composite electrodes with multiply layered structure possess a high specific capacitance of 325 F g(-1) at a current density of 0.2 A g(-1), and an excellent rate capability with a capacitance retention of 70% at a high current density of 5.0 A g(-1). The superior electrochemical performance is mainly due to the unique electrode with improved ion- and electron-transportation pathways as well as the efficient utilization of active materials and electrode robustness. The excellent electrochemical performance and the low cost property endow this flexible nanocomposite electrode with great promise in applications of flexible supercapacitors. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:357 / 364
页数:8
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