Calorimetric investigations on stoichiometric barium and uranium oxides

被引：3

作者：

Dash, Smruti ^{[1
]}

Singh, Ziley ^{[1
]}

机构：

[1] Bhabha Atom Res Ctr, Prod Dev Div, Bombay 400085, Maharashtra, India

来源：

JOURNAL OF NUCLEAR MATERIALS | 2010年 / 404卷 / 01期

关键词：

THERMODYNAMIC PROPERTIES; STANDARD ENTHALPIES; CRYSTAL-STRUCTURE; HEAT-CAPACITY; PHASES; BAUO4;

D O I：

10.1016/j.jnucmat.2010.06.019

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Heat capacities and enthalpy increments of barium uranates BaU2O7(s), Ba2U3O11(s), Ba2875UO5875(s) and Ba3UO6(s) were measured using a differential scanning calorimeter and a high-temperature Calvet calorimeter The heat capacities and enthalpy increments were measured in the temperature range 126-304 K and 299-1011 K. respectively A set of self consistent thermodynamic functions such as entropy, Gibbs energy function, heat capacity and Gibbs energy and enthalpy of formation values for BaU2O7(s), Ba2U3O11(s). Baz 875U05875(s) and Ba3U06(s) have been computed for the first time using the data obtained in the present study and other available experimental data (C) 2010 Elsevier B V All rights reserved

引用

页码：9 / 18

页数：10

共 27 条

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