Copper-catalyzed C-S direct cross-coupling of thiols with 5-arylpenta-2,4-dienoic acid ethyl ester

被引：8

作者：

Cai, Rongrong ^{[1
]}

Zhou, Zhuoda ^{[1
]}

Chai, Qianqian ^{[1
]}

Zhu, Yueer ^{[1
]}

Xu, Runsheng ^{[1
]}

机构：

[1] Zhejiang A&F Univ, Jiyang Coll, Dept Biol & Environm, Shaoxing 311800, Zhejiang, Peoples R China

来源：

RSC ADVANCES | 2018年 / 8卷 / 47期

基金：

中国国家自然科学基金;

关键词：

H BOND FUNCTIONALIZATION; ACTIVATED ALKENES; SULFENYLATION; OXIDATION; ACYLATION; PYRROLES; ALKYNES;

D O I：

10.1039/c8ra05311a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A selective copper (Cu)-catalyzed C-S bond direct cross-coupling of thiols with 5-arylpenta-2,4-dienoic acid ethyl ester was developed. Notably, various biologically active 5-phenyl-3-phenylsulfanylpenta-2,4-dienoic acid ethyl ester derivatives were efficiently synthesized under moderate conditions. Finally, a plausible Cu(I)/Cu(III) reaction mechanism was proposed.

引用

页码：26828 / 26836

页数：9

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