Fe2O3-Cr2O3 system revised

被引:0
作者
Grygar, T [1 ]
Bezdicka, P
Dedecek, J
Petrovsky, E
Schneeweiss, O
机构
[1] Acad Sci Czech Republ, Inst Inorgan Chem, CZ-25068 Rez, Czech Republic
[2] Acad Sci Czech Republ, J Heyrovsky Inst Phys Chem, Prague 18223, Czech Republic
[3] Acad Sci Czech Republ, Inst Geophys, Prague 14131, Czech Republic
[4] Acad Sci Czech Republ, Inst Phys Mat, Brno 61662, Czech Republic
关键词
solid solutions; Vegard law; iron oxide; chromium oxide;
D O I
暂无
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Hematite (a-Fe2O4) and eskolaite (Cr2O3) are typical examples of isostructural oxides with non-linear change of the lattice parameters in their solid solutions. This series was synthesized and characterized by X-ray and neutron powder diffraction, and Mossbauer and electronic spectroscopies. A region of the d-d electron transition of Fe(III) ions in near IR region (about 1000 nm) were found to be suitable for the solid solution characterization, because the transition does not suffer from strong overlaps of Fe(III) and Cr(III) transitions in electronic spectra in the Vs spectral range. Lattice parameters, verified by the comparison to data available in literature, showed that in several cases in the last decade solids of questionable quality were obtained and discussed in the hematite-eskolaite system. Neither X-ray nor neutron diffraction indicated cation ordering, hypothesized in two reports in 1990's. Magnetic structure of the solid solution at 0 < x < 0.6, where x = Cr/(Cr + Fe), is similar to that of hematite, but a different, yet unidentified magnetic ordering involving Fe(III) ions is established in solid solution x = 0.8 below its Neel temperature (about 150 K).
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页码:32 / 39
页数:8
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