Carbon-supported single-atom catalysts for advanced rechargeable metal-air batteries

被引：38

作者：

Xia, Qing ^{[1
]}

Zhai, Yanjie ^{[2
]}

Zhao, Lanling ^{[3
]}

Wang, Jun ^{[1
]}

Li, Deyuan ^{[1
]}

Zhang, Lili ^{[4
]}

Zhang, Jintao ^{[1
]}

机构：

[1] Shandong Univ, Sch Chem & Chem Engn, Key Lab Colloid & Interface Chem, Minist Educ, Jinan 250100, Shandong, Peoples R China

[2] Hong Kong Polytech Univ, Dept Mech Engn, Hung Hom, Kowloon, Hong Kong, Peoples R China

[3] Shandong Univ, Sch Phys, Jinan 250100, Shandong, Peoples R China

[4] ASTAR, Inst Chem & Engn Sci, 1 Pesek Rd, Jurong Isl 627833, Singapore

来源：

ENERGY MATERIALS | 2022年 / 2卷 / 03期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

Single-atom catalysts; carbon supports; electrodes; electrocatalysis; Zn-and Li-air batteries; OXYGEN REDUCTION REACTION; ENERGY-STORAGE; ACTIVE-SITES; EFFICIENT; ELECTROCATALYSTS; CATHODE; GRAPHENE; MECHANISM; STRATEGY; PERFORMANCE;

D O I：

10.20517/energymater.2022.13

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

To address the fossil energy crisis and environmental problems, the urgent demand for clean energy has promoted the rapid development of advanced rechargeable metal-air batteries based on the redox reaction couples of gases, such as the oxygen reduction, oxygen evolution, carbon dioxide reduction and carbon dioxide evolution reactions. High-efficiency electrocatalysts are highly desirable to enhance the conversion efficiency of these reactions for enhancing battery performance. Significant advances in single-atom catalysts (SACs) on carbon matrices have been witnessed in recent years as attractive and unique systems to improve the electrocatalytic activities for highperformance rechargeable Zn-and Li-air batteries. This review summarizes the latest achievements in the applications of carbon-supported SACs in metal-air batteries, with a particular focus on the rational design of SACs and their fundamental electrocatalytic mechanism at the atomic level. The future development and perspectives of SACs in the field of metal-air batteries are also discussed.

引用

页数：24

共 153 条

[1] A lithium-oxygen battery with a long cycle life in an air-like atmosphere [J].

Asadi, Mohammad ;

Sayahpour, Baharak ;

Abbasi, Pedram ;

Ngo, Anh T. ;

Karis, Klas ;

Jokisaari, Jacob R. ;

Liu, Cong ;

Narayanan, Badri ;

Gerard, Marc ;

Yasaei, Poya ;

Hu, Xuan ;

Mukherjee, Arijita ;

Lau, Kah Chun ;

Assary, Rajeev S. ;

Khalili-Araghi, Fatemeh ;

Klie, Robert F. ;

Curtiss, Larry A. ;

Salehi-Khojin, Amin .

NATURE, 2018, 555 (7697) :502-+

[2]

Aurbach D, 2016, NAT ENERGY, V1, DOI [10.1038/nenergy.2016.128, 10.1038/NENERGY.2016.128]

[3] A Critical Review on Functionalization of Air-Cathodes for Nonaqueous Li-O2 Batteries [J].

Balaish, Moran ;

Jung, Ji-Won ;

Kim, Il-Doo ;

Ein-Eli, Yair .

ADVANCED FUNCTIONAL MATERIALS, 2020, 30 (18)

[4] The dynamics of overlayer formation on catalyst nanoparticles and strong metal-support interaction [J].

Beck, Arik ;

Huang, Xing ;

Artiglia, Luca ;

Zabilskiy, Maxim ;

Wang, Xing ;

Rzepka, Przemyslaw ;

Palagin, Dennis ;

Willinger, Marc-Georg ;

van Bokhoven, Jeroen A. .

NATURE COMMUNICATIONS, 2020, 11 (01)

[5] Non-Aqueous and Hybrid Li-O2 Batteries [J].

Black, Robert ;

Adams, Brian ;

Nazar, L. F. .

ADVANCED ENERGY MATERIALS, 2012, 2 (07) :801-815

[6]

Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/NMAT3191, 10.1038/nmat3191]

[7] Recent advances in air electrodes for Zn-air batteries: electrocatalysis and structural design [J].

Cai, Xiaoyi ;

Lai, Linfei ;

Lin, Jianyi ;

Shen, Zexiang .

MATERIALS HORIZONS, 2017, 4 (06) :945-976

[8] Can N, S Cocoordination Promote Single Atom Catalyst Performance in CO2RR? Fe-N2S2 Porphyrin versus Fe-N4 Porphyrin [J].

Cao, Shoufu ;

Wei, Shuxian ;

Wei, Xiaofei ;

Zhou, Sainan ;

Chen, Hongyu ;

Hu, Yuying ;

Wang, Zhaojie ;

Liu, Siyuan ;

Guo, Wenyue ;

Lu, Xiaoqing .

SMALL, 2021, 17 (29)

[9] Recent Progress on Stability Enhancement for Cathode in Rechargeable Non-Aqueous Lithium-Oxygen Battery [J].

Chang, Zhi-wen ;

Xu, Ji-jing ;

Liu, Qing-chao ;

Li, Lin ;

Zhang, Xin-bo .

ADVANCED ENERGY MATERIALS, 2015, 5 (21)

[10] Zinc-Mediated Template Synthesis of Fe-N-C Electrocatalysts with Densely Accessible Fe-Nx Active Sites for Efficient Oxygen Reduction [J].

Chen, Guangbo ;

Liu, Pan ;

Liao, Zhongquan ;

Sun, Fanfei ;

He, Yanghua ;

Zhong, Haixia ;

Zhang, Tao ;

Zschech, Ehrenfried ;

Chen, Mingwei ;

Wu, Gang ;

Zhang, Jian ;

Feng, Xinliang .

ADVANCED MATERIALS, 2020, 32 (08)

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