Circularly polarized luminescence from open- and closed-style axially chiral amphipathic binaphthyl fluorophores in water

被引：9

作者：

Kitatobe, Takumi ^{[1
]}

Mimura, Yuki ^{[1
]}

Tsujimoto, Shintaro ^{[1
]}

Tajima, Nobuo ^{[2
]}

Fujiki, Michiya ^{[3
]}

Imai, Yoshitane ^{[1
]}

机构：

[1] Kindai Univ, Fac Sci & Engn, Dept Appl Chem, 3-4-1 Kowakae, Higashiosaka, Osaka 5778502, Japan

[2] Natl Inst Mat Sci, Computat Mat Sci Ctr, 1-2-1 Sengen, Tsukuba, Ibaraki 3050047, Japan

[3] Nara Inst Sci & Technol, Grad Sch Mat Sci, Ikoma, Nara 6300192, Japan

来源：

TETRAHEDRON | 2017年 / 73卷 / 49期

关键词：

Amphipathicity; Binaphthyl; Chirality; Circularly polarized luminescence; Fluorescence; CORRELATED MOLECULAR CALCULATIONS; GAUSSIAN-BASIS SETS; OPTICAL-ACTIVITY; CPL PROPERTIES; POLYMERS; SOLVATION; DICHROISM; COMPLEXES; STATES; CD;

D O I：

10.1016/j.tet.2017.10.036

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral, ionic C-2-symmetric binaphthyl fluorophores with amphipathic "property can emit circularly polarized luminescence (CPL) in the near-UV region when dissolved in either water or methanol. Despite the same axial chirality (R or S) of the binaphthyl units, the open- and closed-style fluorophores induced sign inversion of CPL and circular dichroism (CD) signals in water. The dihedral angle of the binaphthyl C-2-axis appears to determine the signs of CPL and CD signals even in water. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：6856 / 6862

页数：7

共 9 条

[1] Circularly Polarized Luminescence of Chiral Binaphthyl with Achiral Terthiophene Fluorophores
Taniguchi, Naoya
Nakabayashi, Kazuki
Harada, Takunori
Tajima, Nobuo
Shizuma, Motohiro
Fujiki, Michiya
Imai, Yoshitane
CHEMISTRY LETTERS, 2015, 44 (05) : 598 - 600
[2] Control of Circularly Polarized Luminescence by Using Open- and Closed-Type Binaphthyl Derivatives with the Same Axial Chirality
Kimoto, Takaya
Tajima, Nobuo
Fujiki, Michiya
Imai, Yoshitane
CHEMISTRY-AN ASIAN JOURNAL, 2012, 7 (12) : 2836 - 2841
[3] Circularly polarized luminescence from axially chiral binaphthalene-bridged BODIPY
Liu, Zhipeng
Jiang, Zhiyong
He, Chengkun
Chen, Yuncong
Guo, Zijian
DYES AND PIGMENTS, 2020, 181
[4] Circularly Polarized Luminescence from Axially Chiral BODIPY DYEmers: An Experimental and Computational Study
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Bruhn, Torsten
Guido, Ciro A.
Ahrens, Johannes
Broering, Martin
Di Bari, Lorenzo
Pescitelli, Gennaro
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[5] Reversal Circularly Polarized Luminescence of AIE-Active Chiral Binaphthyl Molecules from Solution to Aggregation
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Shen, Dong
Zhang, Wenjie
Zhang, Hongxing
Zhu, Chengjian
Cheng, Yixiang
CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (38) : 13196 - 13200
[6] Amplification effect of circularly polarized luminescence induced from binaphthyl-based zinc(ii) chiral coordination polymers
Wang, Yuxiang
Li, Xiaojing
Yang, Lan
Sun, Wei-Yin
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MATERIALS CHEMISTRY FRONTIERS, 2018, 2 (03) : 554 - 558
[7] A comparison of circularly polarized luminescence (CPL) and circular dichroism (CD) characteristics of four axially chiral binaphthyl-2,2′-diyl hydrogen phosphate derivatives
Amako, Tomoyuki
Kimoto, Takaya
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Fujiki, Michiya
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[8] Near Infared Circularly Polarized Luminescence From Water Stable Organic Nanoparticles Containing a Chiral Yb(III) Complex
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Nardon, Chiara
Willis, Oliver G.
Zinna, Francesco
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CHEMISTRY-A EUROPEAN JOURNAL, 2022, 28 (37)
[9] Water-soluble chiral tetrazine derivatives: towards the application of circularly polarized luminescence from upper-excited states to photodynamic therapy
He, Tingchao
Ren, Can
Luo, Yu
Wang, Qi
Li, Junzi
Lin, Xiaodong
Ye, Chuanxiang
Hu, Wenbo
Zhang, Junmin
CHEMICAL SCIENCE, 2019, 10 (15) : 4163 - 4168

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