TRANSFORMATION OF AMINES TO OXIMES USING HETEROGENEOUS NANOCRYSTALLINE TITANIUM(IV) OXIDE AS A GREEN CATALYST

被引：23

作者：

Kidwai, Mazaahir ^{[1
]}

Bhardwaj, Saurav ^{[1
]}

机构：

[1] Univ Delhi, Dept Chem, Green Chem Res Lab, Delhi 110007, India

来源：

SYNTHETIC COMMUNICATIONS | 2011年 / 41卷 / 18期

关键词：

Green chemistry; nanoparticles; oxidation; oxime; REDUCTION; OXIDATION; PHOTOCATALYSIS; REAGENT; TS-1; H2O2; MGO;

D O I：

10.1080/00397911.2010.515339

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidation of amines into corresponding oximes has been described using heterogeneous nanocrystalline titanium(IV) oxide as catalyst and H2O2 as oxidizing agent in quantitative yields. Both aromatics and aliphatic amines undergo oxidation. Besides this, nanocrystalline TiO2 was recovered and used for further reactions. Hence our present protocol is economical and clean and uses green reagent, solvent, and catalyst.

引用

页码：2655 / 2662

页数：8

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