Decay of correlations in fluids: The one-component plasma from Debye-Huckel to the asymptotic-high-density limit

被引:44
作者
de Carvalho, RJFL
Evans, R
Rosenfeld, Y
机构
[1] Univ Bristol, HH Wills Phys Lab, Bristol BS8 1TL, Avon, England
[2] Ecole Normale Super Lyon, Phys Lab, F-69364 Lyon 07, France
[3] Nucl Res Ctr Negev, Dept Phys, IL-84190 Beer Sheva, Israel
来源
PHYSICAL REVIEW E | 1999年 / 59卷 / 02期
关键词
D O I
10.1103/PhysRevE.59.1435
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
The decay of structural correlations in the classical one-component plasma is analyzed by calculating the poles of the Fourier transform of the total (pairwise) correlation function h(r) for two integral equation theories, the soft mean spherical approximation and the hypernetted chain (HNC). We show that for all except the largest values of the plasma coupling constant Gamma, the leading-order pole contribution provides an accurate description of h(r) at intermediate range, as well as the ultimate asymptotic decay. The crossover from monotonic decay at weak coupling to exponentially damped oscillatory decay at strong coupling is shown to arise from the same mechanism as that which occurs for charge correlations in binary ionic fluids. We calculate the values of Gamma at which the crossover occurs in the two theories. The role of higher-order poles and (within the HNC) other singularities in determining the intermediate range behavior of h(r) for strong coupling is discussed. We investigate the properties of the solutions of the integral equations in the strong coupling, Gamma-->infinity, asymptotic high-density limit (AHDL). Pade approximants are employed in order to test the validity of the scaling laws proposed for the potential energy, direct correlation function, and for the poles and their contributions to h(r) in the AHDL. Our numerical results provide strong support for the validity of the theoretical predictions concerning the AHDL.
引用
收藏
页码:1435 / 1451
页数:17
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