EPR study of platinum supported on NaY

被引:8
作者
Schmauke, T [1 ]
Möller, E [1 ]
Roduner, E [1 ]
机构
[1] Univ Stuttgart, Inst Phys Chem, D-70550 Stuttgart, Germany
关键词
D O I
10.1039/a805409f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pt/NaY was prepared by the aqueous ion-exchange method and investigated by EPR spectroscopy. After reduction with Hz using a static system, an orthorhombic EPR signal was observed with g(1) = 2.531, g(2) = 2.322, g(3) = 2.062, coaxial with the hyperfine components a(1) = 64.9 G, a(2) = 74.6 G, a(3) = 72.6 G; this signal is assigned to Pt+ ions. Typical cation sites for location in the supercages are excluded for symmetry reasons.
引用
收藏
页码:2589 / 2590
页数:2
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