The crystal structure of Yb2(SO4)3•3H2O and its decomposition product, β-Yb2(SO4)3

被引：8
|
作者：
Mills, Stuart J. [1 ,2 ]
Petricek, Vaclav [3 ]
Kampf, Anthony R. [2 ]
Herbst-Imer, Regine [4 ]
Raudsepp, Mati [1 ]
机构：
[1] Univ British Columbia, Dept Earth & Ocean Sci, Vancouver, BC V6T 1Z4, Canada
[2] Nat Hist Museum Los Angeles Cty, Dept Mineral Sci, Los Angeles, CA 90007 USA
[3] Acad Sci Czech Republ, Inst Phys, Vvi, Prague 18221, Czech Republic
[4] Univ Gottingen, Dept Struct Chem, D-37077 Gottingen, Germany
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2011年 / 184卷 / 09期
基金：
加拿大自然科学与工程研究理事会;
关键词：
Crystal structure; Hydrothermal synthesis; Rare earth; Sulphate; Ytterbium; Yttrium; THERMAL-BEHAVIOR; SULFATE; CHEMISTRY; YB;
D O I：
10.1016/j.jssc.2011.06.018
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Yb-2(SO4)(3)center dot 3H(2)O, synthesised by hydrothermal methods at 220(2) degrees C, has been investigated by single crystal X-ray diffraction. Yb-2(SO4)(3)center dot 3H(2)O crystallises in space group Cmc2(1) and is isostructural with Lu-2(SO4)(3)center dot 3H(2)O. The crystal structure has been refined to R-1=0.0145 for 3412 reflections [F-o > 3 sigma(F)]. and 0.0150 for all 3472 reflections. The structure of Yb-2(SO4)(3)center dot 3H(2)O is a complex framework of YbO6 octahedra, YbO8 and YbO5(H2O)(3) polyhedra and SO4 tetrahedra. Thermal data shows that Yb-2(SO4)(3)center dot 3H(2)O decomposes between 120 and 190 degrees C to form beta-Yb-2(SO4)(3). The structure of a twinned crystal of beta-Yb-2(SO4)(3) was solved and refined using an amplimode refinement in R3c with an R-1=0.0755 for 8944 reflections [F-o > 3 sigma(F)], and 0.1483 for all 16,361 reflections. beta-Yb-2(SO4)(3) has a unique structural topology based on a 3D network of pinwheels. (C) 2011 Elsevier Inc. All rights reserved.
引用
收藏
页码：2322 / 2328
页数：7
相关论文
共 50 条
  • [21] THE CRYSTAL-STRUCTURE OF FEDOTOVITE, K2CU3O(SO4)3
    STAROVA, GL
    FILATOV, SK
    FUNDAMENSKY, VS
    VERGASOVA, LP
    MINERALOGICAL MAGAZINE, 1991, 55 (381) : 613 - 616
  • [22] Crystal Structure and Theoretical Analysis of Cs2Ca3(SO4)4
    Fang, Penglin
    Tang, Wenyue
    Shen, Yaoguo
    Hong, Jinquan
    Li, Yongming
    Jia, Junrong
    CRYSTALS, 2022, 12 (02)
  • [23] Reinvestigation of the structure of (ND4)3D(SO4)2 and (NH4)3H(SO4)2 at room temperature
    Tamura, I
    Noda, Y
    Morii, Y
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1999, 60 (8-9) : 1411 - 1414
  • [24] Crystal structure of NH4[La(SO4)(2)(H2O)]
    Benslimane, Meriem
    Redjel, Yasmine Kheira
    Merazig, Hocine
    Daran, Jean-Claude
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 663 - +
  • [25] Exploration of the structural, spectroscopic and thermal properties of double sulfate monohydrate NaSm(SO4)2•H2O and its thermal decomposition product NaSm(SO4)2
    Denisenko, Yuriy G.
    Sedykh, Alexander E.
    Basova, Sofia A.
    Atuchin, V. Victor
    Molokeev, Maxim S.
    Aleksandrovsky, Aleksandr S.
    Krylov, Alexander S.
    Oreshonkov, Aleksandr S.
    Khritokhin, Nikolay A.
    Sal'nikova, Elena I.
    Andreev, V. Oleg
    Muller-Buschbaum, Klaus
    ADVANCED POWDER TECHNOLOGY, 2021, 32 (11) : 3943 - 3953
  • [26] Successive Crystallization of Organically Templated Uranyl Sulfates: Synthesis and Crystal Structures of [pyH](H3O)[(UO2)3(SO4)4(H2O)2], [pyH]2[(UO2)6(SO4)7(H2O)], and [pyH]2[(UO2)2(SO4)3]
    Nazarchuk, Evgeny V.
    Charkin, Dmitri O.
    Siidra, Oleg I.
    CHEMENGINEERING, 2021, 5 (01) : 1 - 8
  • [27] Glass formation in the systems Al2(SO4)3-MSO4-H2O (M = Cd2+, Zn2+, Mg2+) and Al2(SO4)3-Fe2(SO4)3-H2O
    Kirilenko, I. A.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2012, 57 (10) : 1374 - 1378
  • [28] Noncentrosymmetric K2Mn3(SO4)3F2•4H2O and Rb2Mn3(SO4)3F2•2H2O with pseudo-KTP structures
    Zhou, Yang
    Li, Yanqiang
    Ding, Qingran
    Liu, Youchao
    Chen, Yangxin
    Liu, Xitao
    Huang, Xiaoying
    Li, Lina
    Zhao, Sangen
    Luo, Junhua
    CHINESE CHEMICAL LETTERS, 2021, 32 (01) : 263 - 265
  • [29] The crystal structure of argentojarosite, AgFe3(SO4)2(OH)6
    Groat, LA
    Jambor, JL
    Pemberton, BC
    CANADIAN MINERALOGIST, 2003, 41 : 921 - 928
  • [30] Two novel organic amine templated lanthanide sulfates: Layer H3DETA • [Nd(H2O)(SO4)3] and chain-like H3DETA • [Ho(H2O)2(SO4)3]
    Li, Y.
    Hu, Y.
    Shi, C.
    Li, D.
    Jin, L.
    Ran, X.
    Zhang, L.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2010, 36 (11) : 844 - 852
12345