The crystal structure of Yb2(SO4)3•3H2O and its decomposition product, β-Yb2(SO4)3

被引：8
|
作者：
Mills, Stuart J. [1 ,2 ]
Petricek, Vaclav [3 ]
Kampf, Anthony R. [2 ]
Herbst-Imer, Regine [4 ]
Raudsepp, Mati [1 ]
机构：
[1] Univ British Columbia, Dept Earth & Ocean Sci, Vancouver, BC V6T 1Z4, Canada
[2] Nat Hist Museum Los Angeles Cty, Dept Mineral Sci, Los Angeles, CA 90007 USA
[3] Acad Sci Czech Republ, Inst Phys, Vvi, Prague 18221, Czech Republic
[4] Univ Gottingen, Dept Struct Chem, D-37077 Gottingen, Germany
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2011年 / 184卷 / 09期
基金：
加拿大自然科学与工程研究理事会;
关键词：
Crystal structure; Hydrothermal synthesis; Rare earth; Sulphate; Ytterbium; Yttrium; THERMAL-BEHAVIOR; SULFATE; CHEMISTRY; YB;
D O I：
10.1016/j.jssc.2011.06.018
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Yb-2(SO4)(3)center dot 3H(2)O, synthesised by hydrothermal methods at 220(2) degrees C, has been investigated by single crystal X-ray diffraction. Yb-2(SO4)(3)center dot 3H(2)O crystallises in space group Cmc2(1) and is isostructural with Lu-2(SO4)(3)center dot 3H(2)O. The crystal structure has been refined to R-1=0.0145 for 3412 reflections [F-o > 3 sigma(F)]. and 0.0150 for all 3472 reflections. The structure of Yb-2(SO4)(3)center dot 3H(2)O is a complex framework of YbO6 octahedra, YbO8 and YbO5(H2O)(3) polyhedra and SO4 tetrahedra. Thermal data shows that Yb-2(SO4)(3)center dot 3H(2)O decomposes between 120 and 190 degrees C to form beta-Yb-2(SO4)(3). The structure of a twinned crystal of beta-Yb-2(SO4)(3) was solved and refined using an amplimode refinement in R3c with an R-1=0.0755 for 8944 reflections [F-o > 3 sigma(F)], and 0.1483 for all 16,361 reflections. beta-Yb-2(SO4)(3) has a unique structural topology based on a 3D network of pinwheels. (C) 2011 Elsevier Inc. All rights reserved.
引用
收藏
页码：2322 / 2328
页数：7
相关论文
共 50 条
  • [1] Preparation, crystal structure and thermal decomposition character of [Ni(CHZ)3]SO4•3H2O
    Zhang Jin
    Zhang Tong-Lai
    Yang Li
    Zhang Jian-Guo
    Cui Yan
    ACTA PHYSICO-CHIMICA SINICA, 2008, 24 (05) : 760 - 766
  • [2] Crystal structure of Na3Fe(SO4)3: A high-temperature product (∼400 °C) of sideronatrite [Na2Fe(SO4)2OH•3H2O]
    Scordari, Fernando
    Ventruti, Gennaro
    Gualtieri, Alessandro F.
    Lausi, Andrea
    AMERICAN MINERALOGIST, 2011, 96 (07) : 1107 - 1111
  • [3] (H3O)Nd(SO4)2
    Zhang, Zaichao
    Zhang, Zhibin
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2010, 66 : I9 - I11
  • [4] Synthesis and crystal structures of yttrium sulfates Y(OH)(SO4), Y(SO4)F, YNi(OH)3(SO4)-II and Y2Cu(OH)3(SO4)2F• H2O
    Wang, XQ
    Liu, LM
    Ross, K
    Jacobson, AJ
    SOLID STATE SCIENCES, 2000, 2 (01) : 109 - 118
  • [5] Syntheses, crystal structures and optical spectroscopy of Ln2(SO4)3 • 8H2O (Ln=Ho, Tm) and Pr2(SO4)3 • 4H2O
    Kazmierczak, Karolina
    Hoeppe, Henning A.
    JOURNAL OF SOLID STATE CHEMISTRY, 2011, 184 (05) : 1221 - 1226
  • [6] Crystal Structure, Vibrational, Spectroscopic and Thermochemical Properties of Double Sulfate Crystalline Hydrate [CsEu(H2O)3(SO4)2]•H2O and Its Thermal Dehydration Product CsEu(SO4)2
    Denisenko, Yuriy G.
    Molokeev, Maxim S.
    Oreshonkov, Aleksandr S.
    Krylov, Alexander S.
    Aleksandrovsky, Aleksandr S.
    Azarapin, Nikita O.
    Andreev, Oleg, V
    Razumkova, Illaria A.
    Atuchin, Victor V.
    CRYSTALS, 2021, 11 (09)
  • [7] Sulfates of the Refractory Metals: Crystal Structure and Thermal Behavior of Nb2O2(SO4)3, MoO2(SO4), WO(SO4)2, and Two Modifications of Re2O5(SO4)2
    Betke, Ulf
    Wickleder, Mathias S.
    INORGANIC CHEMISTRY, 2011, 50 (03) : 858 - 872
  • [8] THE ATOMIC STRUCTURE OF (H3O)Fe3+(SO4)2 AND RHOMBOCLASE, (H5O2)Fe3+(SO4)2•2H2O
    Peterson, Ronald C.
    Valyashko, Elena
    Wang, Ruiyao
    CANADIAN MINERALOGIST, 2009, 47 (03) : 625 - 634
  • [9] Oxidizing Rhodium with Sulfuric Acid: The Sulfates Rh2(SO4)3 and Rh2(SO4)3•2H2O
    Schwarzer, Stefan
    Betke, Annika
    Logemann, Christian
    Wickleder, Mathias S.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (03) : 752 - 758
  • [10] Syntheses, crystal structures, and thermal behavior of Er2(SO4)3 • 8H2O and Er2(SO4)3 • 4H2O
    Wickleder, MS
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (09): : 1548 - 1555
12345