Ultrasmall Iron Oxide Nanoparticles for Biomedical Applications: Improving the Colloidal and Magnetic Properties

被引:85
作者
Costo, Rocio [1 ]
Bello, Valentina [2 ]
Robic, Caroline [3 ]
Port, Marc [3 ]
Marco, Jose F. [4 ]
Puerto Morales, M. [1 ]
Veintemillas-Verdaguer, Sabino [1 ]
机构
[1] Inst Ciencia Mat Madrid CSIC, Madrid 28049, Spain
[2] Univ Padua, Dipartimento Fis, I-35131 Padua, Italy
[3] Guerbet Res, F-95943 Roissy, France
[4] Inst Quim Fis Rocasolano CSIC, Madrid 28006, Spain
关键词
LASER PYROLYSIS; GAMMA-FE2O3; NANOPARTICLES; MAGHEMITE NANOPARTICLES; SURFACE; SIZE; FERROFLUIDS; POINTS; CHARGE;
D O I
10.1021/la203428z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A considerable increase in the saturation magnetization, Ms (40%), and initial susceptibility of ultrasmall (<5 nm) iron oxide nanoparticles prepared by laser pyrolysis was obtained through an optimized acid treatment. Moreover, a significant enhancement in the colloidal properties, such as smaller aggregate sizes in aqueous media and increased surface charge densities, was found after this chemical protocol. The results are consistent with a reduction in nanoparticle surface disorder induced by a dissolution recrystallization mechanism.
引用
收藏
页码:178 / 185
页数:8
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