A new 3D Mn(II) coordination polymer: Synthesis, crystal structure and photoelectrical property

被引：4
作者：
Luo, Yanan [1 ]
Kong, Miao [1 ]
Ren, Hao [2 ]
Gao, Yongwei [1 ]
Yu, Xiaoyang [1 ]
机构：
[1] Jilin Inst Chem Technol, Coll Chem & Pharmaceut Engn, Jilin 132022, Jilin, Peoples R China
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 132013, Jilin, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2020年 / 511卷
基金：
美国国家科学基金会;
关键词：
Solvothermal synthesis; Azobenzene-4,4 '-dicarboxylate; Fluorescent property; Photoelectrical property; SENSITIZED SOLAR-CELL; DYE; ACID; PERFORMANCES; LIGAND; CHAINS;
D O I：
10.1016/j.ica.2020.119834
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
By using azobenzene-4,4'-dicarboxylate (H2L) ligand, a new coordination polymer, formulated as [Mn(L) (H2O)(2)](n) (1), has been synthesized successfully under solvothermal conditions. Complex 1 exhibits a three-dimensional (3D) framework with (4,4)-connected {6(.)(5)8} topology. Moreover, the fluorescent property of complex 1 has been investigated. The electrochemical study displays that complex 1 forms a re-organization of energy level due to its single-crystal structure in the tandem structure of complex 1/N719/TiO2. The result demonstrates that the complex 1/N719/TiO2 solar cell exhibited excellent photovoltaic performance with the photoelectric conversion efficiency of 3.70% under 100 mW cm(-2) illumination.
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页数：6
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