9-[4,5-Bis(benzylsulfanyl)-1,3-dithiol-2-ylidene]-4,5-diazafluorene

被引:1
作者
Zhong, Xu-Dong [1 ]
Zhu, Yu-Lan [1 ,2 ]
Wu, Xue [1 ]
Jin, Jing-Yi [1 ]
Tang, Xue-Ling [1 ]
机构
[1] Yanbian Univ, Dept Chem, Coll Sci, Yanji 133002, Peoples R China
[2] Huaiyin Teachers Coll, Jiangsu Key Lab Chem Low Dimens Mat, Huaian 223300, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词
D O I
10.1107/S1600536808018667
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In rhe title compound, C28H20N2S4, the 1,3-dithiol-2-ylidene and 4,5-diazafluoren-9-one(dafone) groups are almost coplanar, making a dihedral angle of only 5.65(4)degrees. The two benzyl groups are on different sides of the 1,3-dithiol-2-ylidene ring, forming a dihedral angle of 35.54 (2)degrees.
引用
收藏
页码:O1353 / U2702
页数:10
相关论文
共 11 条
[1]   The interplay of inverted redox potentials and aromaticity in the oxidized states of new π-electron donors:: 9-(1,3-dithiol-2-ylidene)fluorene and 9-(1,3-dithiol-2-ylidene)thioxanthene derivatives [J].
Amriou, S ;
Wang, CS ;
Batsanov, AS ;
Bryce, MR ;
Perepichka, DF ;
Ortí, E ;
Viruela, R ;
Vidal-Gancedo, J ;
Rovira, C .
CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (12) :3389-3400
[2]   Sequential generation of one-dimensional networks based on a differentiated bischelate-type ligand bearing both 4,5-diazafluorene and dithiolene units [J].
Baudron, Stephane A. ;
Hosseini, Mir Wais .
INORGANIC CHEMISTRY, 2006, 45 (14) :5260-5262
[3]  
*BRUK AXS INC, 2000, SADABS
[4]  
Bruker, 2004, APEX2 SAINT
[5]  
Farrugia L.J., 1997, J APPL CRYSTALLOGR, V30, P565
[6]   9-Oxo-4,5-diazoniafluorene sulfate [J].
Rillema, D. Paul ;
Kirgan, Robert ;
Moore, Curtis .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 :O3740-U2403
[7]  
SAKO K, 1996, MOL CRYST LIQ CRYST, V285, P4804
[8]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122
[9]   Single-crystal structure validation with the program PLATON [J].
Spek, AL .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2003, 36 :7-13
[10]   4,5-diazafluorene-incorporated ter(9,9-diarylfluorene): A novel molecular doping strategy for improving the electron injection property of a highly efficient OLED blue emitter [J].
Wong, KT ;
Chen, RT ;
Fang, FC ;
Wu, CC ;
Lin, YT .
ORGANIC LETTERS, 2005, 7 (10) :1979-1982