Electronic States of Acetic Acid in a Binary Mixture of Acetic Acid and 1-Methylimidazole Depend on the Environment

被引：2

作者：

Yoshimura, Noriko ^{[1
,2
]}

Takahashi, Osamu ^{[2
,3
]}

Oura, Masaki ^{[2
]}

Horikawa, Yuka ^{[1
,2
]}

机构：

[1] Yamaguchi Univ, Grad Sch Sci & Technol Innovat, Yamaguchi 7538512, Japan

[2] RIKEN SPring 8 Ctr, Soft Xray Spect Instrumentat Team, Mikazuki, Hyogo 6795148, Japan

[3] Hiroshima Univ, Dept Chem, Grad Sch Sci, Higashihiroshima 7398526, Japan

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2019年 / 123卷 / 06期

关键词：

RAY-EMISSION SPECTROSCOPY; CARBOXYLIC-ACIDS; LIQUID; SPECTRA; PERFORMANCE; WATER;

D O I：

10.1021/acs.jpcb.8b11437

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The unique characteristics of an acetic acid/1-methylimidazole (1-MI) mixture, showing higher electrical conductivity than either neat acetic acid or neat 1-MI, yet consisting of electrically neutral molecules, are reported. We have applied soft X-ray spectroscopy to reveal the electronic states of acetic acid in the acetic acid/1-MI mixture at various mole fractions of acetic acid (Chi(HOAc)). The results show that the amount of acetic acid monomer increases in the region of especially high electrical conductivity and the amount of complex of acetic acid and 1-MI formed by sharing molecular orbitals increases in the low electrical conductivity region.

引用

页码：1332 / 1339

页数：8

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