Electrostatic immobilization of an olefin metathesis pre-catalyst on iron oxide magnetic particles

被引：21

作者：

Byrnes, Matthew J. ^{[1
]}

Hilton, Andrew M. ^{[1
]}

Woodward, Clint P. ^{[1
]}

Jackson, William R. ^{[1
]}

Robinson, Andrea J. ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

来源：

GREEN CHEMISTRY | 2012年 / 14卷 / 01期

关键词：

COUPLING REACTIONS; CHEMISTRY; NANOPARTICLES;

D O I：

10.1039/c1gc16084b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A quaternary ammonium Hoveyda-Grubbs olefin metathesis pre-catalyst has been reversibly immobilized on sulphonic acid-functionalised silica-coated iron oxide magnetic particles to affect ring closing metathesis with easy removal, reuse and regeneration.

引用

页码：81 / 84

页数：4

共 25 条

[1] Separable catalysts in one-pot syntheses for greener chemistry [J].

Abu-Reziq, Raed ;

Wang, Dashan ;

Post, Michael ;

Alper, Howard .

CHEMISTRY OF MATERIALS, 2008, 20 (07) :2544-2550

[2] Well-Defined Silica-Supported Olefin Metathesis Catalysts [J].

Allen, Daryl P. ;

Van Wingerden, Matthew M. ;

Grubbs, Robert H. .

ORGANIC LETTERS, 2009, 11 (06) :1261-1264

[3] Recent advances in the synthesis of supported metathesis catalysts [J].

Buchmeiser, MR .

NEW JOURNAL OF CHEMISTRY, 2004, 28 (05) :549-557

[4] Magnetic nanoparticle-supported Hoveyda-Grubbs catalysts for ring-closing metathesis reactions [J].

Che, Chao ;

Li, Wenzhao ;

Lin, Shengyue ;

Chen, Jiwei ;

Zheng, Jie ;

Wu, Jiun-chen ;

Zheng, Qunxiong ;

Zhang, Guoqing ;

Yang, Zhen ;

Jiang, Biwang .

CHEMICAL COMMUNICATIONS, 2009, (40) :5990-5992

[5] Sustainable concepts in olefin metathesis [J].

Clavier, Herve ;

Grela, Karo ;

Kirschning, Andreas ;

Mauduit, Marc ;

Nalon, Steven P. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (36) :6786-6801

[6] Strategies to immobilize well-defined olefin metathesis catalysts: Supported homogeneous catalysis vs. surface organometallic chemistry [J].

Coperet, C. ;

Basset, J. -M. .

ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (1-2) :78-92

[7] Alkene metathesis: the search for better catalysts [J].

Deshmukh, Prashant H. ;

Blechert, Siegfried .

DALTON TRANSACTIONS, 2007, (24) :2479-2491

[8] Magnetically recoverable osmium catalysts for dihydroxylation of olefins [J].

Fujita, Ken-ichi ;

Umeki, Satoshi ;

Yamazaki, Manabu ;

Ainoya, Taku ;

Tsuchimoto, Teruhisa ;

Yasuda, Hiroyuki .

TETRAHEDRON LETTERS, 2011, 52 (24) :3137-3140

[9] A Magnetically Separable Heterogeneous Deallylation Catalyst: [CpRu(η3-C3H5)(2-pyridinecarboxylato)]PF6 Complex Supported on a Ferromagnetic Microsize Particle Fe3O4@SiO2 [J].

Hirakawa, Takuya ;

Tanaka, Shinji ;

Usuki, Naoki ;

Kanzaki, Hisao ;

Kishimoto, Mikio ;

Kitamura, Masato .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2009, 2009 (06) :789-792

[10] The remarkable metal-catalysed olefin metathesis reaction [J].

Hoveyda, Amir H. ;

Zhugralin, Adil R. .

NATURE, 2007, 450 (7167) :243-251

← 1 2 3 →