Chelation-controlled reduction: an enantioselective synthesis of (-)-tarchonanthuslactone

被引：57

作者：

Sabitha, G ^{[1
]}

Sudhakar, K ^{[1
]}

Reddy, NM ^{[1
]}

Rajkumar, M ^{[1
]}

Yadav, JS ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Div 1, Hyderabad 500007, Andhra Pradesh, India

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 38期

关键词：

chelation-controlled reduction; tarchonanthuslactone; RCM; Wacker oxidation;

D O I：

10.1016/j.tetlet.2005.07.075

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The total synthesis of tarchonanthuslactone (1) has been achieved by two different routes. In the first approach, LiAlH4-LiI reduction and RCM protocols, and in the second approach, Wacker oxidation and LiAlH4-LiI reduction were used as key steps. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：6567 / 6570

页数：4

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