Chelation-controlled reduction: an enantioselective synthesis of (-)-tarchonanthuslactone

被引：57
|
作者：
Sabitha, G [1 ]
Sudhakar, K [1 ]
Reddy, NM [1 ]
Rajkumar, M [1 ]
Yadav, JS [1 ]
机构：
[1] Indian Inst Chem Technol, Organ Div 1, Hyderabad 500007, Andhra Pradesh, India
来源：
TETRAHEDRON LETTERS | 2005年 / 46卷 / 38期
关键词：
chelation-controlled reduction; tarchonanthuslactone; RCM; Wacker oxidation;
D O I：
10.1016/j.tetlet.2005.07.075
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The total synthesis of tarchonanthuslactone (1) has been achieved by two different routes. In the first approach, LiAlH4-LiI reduction and RCM protocols, and in the second approach, Wacker oxidation and LiAlH4-LiI reduction were used as key steps. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6567 / 6570
页数：4
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