Small Molecule/Polymer Blend Organic Transistors with Hole Mobility Exceeding 13 cm2 V-1 s-1

被引:179
作者
Paterson, Alexandra F. [1 ,2 ]
Treat, Neil D. [3 ]
Zhang, Weimin [4 ]
Fei, Zhuping [2 ,5 ]
Wyatt-Moon, Gwenhivir [1 ,2 ]
Faber, Hendrik [1 ,2 ]
Vourlias, George [6 ]
Patsalas, Panos A. [6 ]
Solomeshch, Olga [7 ]
Tessler, Nir [7 ]
Heeney, Martin [2 ,5 ]
Anthopoulos, Thomas D. [1 ,2 ]
机构
[1] Imperial Coll London, Dept Phys, London SW7 2AZ, England
[2] Imperial Coll London, Ctr Plast Elect, London SW7 2AZ, England
[3] Imperial Coll London, Dept Mat, London SW7 2AZ, England
[4] Guangxi Univ Nationalities, Coll Chem & Chem Engn, Nanning 530006, Peoples R China
[5] Imperial Coll London, Dept Chem, London SW7 2AZ, England
[6] Aristotle Univ Thessaloniki, Appl Phys Lab, Dept Phys, GR-54124 Thessaloniki, Greece
[7] Technion Israel Inst Technol, Dept Elect Engn, Sara & Moshe Zisapel Nanoelect Ctr, IL-3200 Haifa, Israel
基金
英国工程与自然科学研究理事会;
关键词
FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; HIGH-PERFORMANCE; SEMICONDUCTING POLYMERS; SOLVENT; MORPHOLOGY;
D O I
10.1002/adma.201601075
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A ternary organic semiconducting blend composed of a small-molecule, a conjugated polymer, and a mole cular p-dopant is developed and used in solution-processed organic transistors with hole mobility exceeding 13 cm(2) V-1 s(-1) (see the Figure). It is shown that key to this development is the incorporation of the p-dopant and the formation of a vertically phase-separated film microstructure.
引用
收藏
页码:7791 / +
页数:9
相关论文
共 52 条
[1]  
Anthopoulos T. D., 2013, WO, Patent No. [2013098648 A1, 2013098648]
[2]   Indacenodithiophene-co-benzothiadiazole Copolymers for High Performance Solar Cells or Transistors via Alkyl Chain Optimization [J].
Bronstein, Hugo ;
Leem, Dong Seok ;
Hamilton, Richard ;
Woebkenberg, Paul ;
King, Simon ;
Zhang, Weimin ;
Ashraf, Raja Shahid ;
Heeney, Martin ;
Anthopoulos, Thomas D. ;
de Mello, John ;
McCulloch, Iain .
MACROMOLECULES, 2011, 44 (17) :6649-6652
[3]  
Bulusheva LG, 1999, J PHYS CHEM A, V103, P9921, DOI 10.1021/jp992037
[4]  
Byrappa K, 2003, SPR S MAT PROC, P335
[5]   Enhanced mobility of poly(3-hexylthiophene) transistors by spin-coating from high-boiling-point solvents [J].
Chang, JF ;
Sun, BQ ;
Breiby, DW ;
Nielsen, MM ;
Sölling, TI ;
Giles, M ;
McCulloch, I ;
Sirringhaus, H .
CHEMISTRY OF MATERIALS, 2004, 16 (23) :4772-4776
[6]   Controlled Growth of Large-Area High-Performance Small-Molecule Organic Single-Crystalline Transistors by Slot-Die Coating Using A Mixed Solvent System [J].
Chang, Jingjing ;
Chi, Chunyan ;
Zhang, Jie ;
Wu, Jishan .
ADVANCED MATERIALS, 2013, 25 (44) :6442-6447
[7]  
Diao Y, 2013, NAT MATER, V12, P665, DOI [10.1038/NMAT3650, 10.1038/nmat3650]
[8]  
Dimitrakopoulos CD, 2002, ADV MATER, V14, P99, DOI 10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO
[9]  
2-9
[10]   Dynamics of Monolayer-Island Transitions in 2,7-Dioctyl-benzothienobenzthiophene Thin Films [J].
Dohr, Michael ;
Werzer, Oliver ;
Shen, Quan ;
Salzmann, Ingo ;
Teichert, Christian ;
Ruzie, Christian ;
Schweicher, Guillaume ;
Geerts, Yves Henri ;
Sferrazza, Michele ;
Resel, Roland .
CHEMPHYSCHEM, 2013, 14 (11) :2554-2559