Cooperation between catalytic sites on a bicipital supported phosphonium phase-transfer catalyst

被引：10

作者：

Clark, JH ^{[1
]}

Tavener, SJ ^{[1
]}

Barlow, SJ ^{[1
]}

机构：

[1] CONTRACT CATALYSTS LTD,PRESCOT L34 9HY,MERSEYSIDE,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 21期

关键词：

D O I：

10.1039/cc9960002429

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel bicipital tetraarylphosphonium salt grafted to silica gel is prepared and characterised, and gives unusually high catalytic rate enhancements in some nucleophilic substitution reactions, which suggest cooperation between the neighbouring phosphonium centres.

引用

页码：2429 / 2430

页数：2

共 9 条

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