Structural and transport properties of doped bismuth titanates and niobates

被引：22

作者：

Sadykov, V. A. ^{[1
,2
]}

Koroleva, M. S. ^{[3
]}

Piir, I. V. ^{[3
]}

Chezhina, N. V. ^{[4
]}

Korolev, D. A. ^{[4
]}

Skriabin, P. I. ^{[1
]}

Krasnov, A. V. ^{[1
]}

Sadovskaya, E. M. ^{[1
,2
]}

Eremeev, N. F. ^{[1
]}

Nekipelov, S. V. ^{[5
]}

Sivkov, V. N. ^{[5
]}

机构：

[1] Boreskov Inst Catalysis SB RAS, Pr Akad Lavrentieva 5, Novosibirsk 630090, Russia

[2] Novosivirsk State Univ, Pirogova Str 2, Novosibirsk 630090, Russia

[3] Inst Chem Komi SC UB RAS, Pervomayskaya St 48, Syktyvkar 167982, Russia

[4] St Petersburg State Univ, Univ Skaya Nab 7-9, St Petersburg 199034, Russia

[5] Komi SC UB RAS, Dept Math, Chernova St 3a, Syktyvkar 167982, Russia

来源：

SOLID STATE IONICS | 2018年 / 315卷

基金：

俄罗斯科学基金会;

关键词：

Bismuth titanates/niobates; Structure; Conductivity; Oxygen mobility; DIELECTRIC-PROPERTIES; BI2TI2O7; PYROCHLORES; RELAXATION; LA;

D O I：

10.1016/j.ssi.2017.12.008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cobalt- or Zn-doped bismuth titanates and Mg + Cu-doped bismuth niobate were synthesized by the method of organic-inorganic precursors combustion. Distribution of dopants over the sites of the pyrochlore structure was elucidated by X-ray powder diffraction structure refinement and pycnometric density analysis. Zinc and cobalt cations are mainly located in Bi sites appearing also in Ti sites at their high content. Mg cations are located only in Nb sites, while Cu cations are equally distributed between Bi and Nb sites. Magnetic susceptibility data confirm Co2+ state of cobalt atoms revealed by NEXAFS. Antiferromagnetic exchange appears when Co atoms enter the titanium sites. Electronic conductivity of p-type dominates for Co-doped samples in the 160-750 degrees C temperature range. The oxygen mobility and surface reactivity were studied by the oxygen isotope hetero-exchange with (CO2)-O-18 in isothermal and temperature-programmed modes. Mobility of the lattice oxygen can be described by a homogeneous model. The oxygen mobility and surface reactivity are comparable for doped bismuth titanates and niobates correlating with conductivity and being the highest for Co and Cu-doped samples with disordered distribution of dopants between lattice sites.

引用

页码：33 / 39

页数：7

共 32 条

[11] CONDUCTION IN TITANATE PYROCHLORES - ROLE OF DOPANTS [J].

KRAMER, S ;

SPEARS, M ;

TULLER, HL .

SOLID STATE IONICS, 1994, 72 :59-66

[12] The conductivity and ionic transport of doped bismuth titanate pyrochlore Bi1.6MxTi2O7 - δ (M - Mg, Sc, Cu) [J].

Krasnov, A. G. ;

Piir, I. V. ;

Koroleva, M. S. ;

Sekushin, N. A. ;

Ryabkov, Y. I. ;

Piskaykina, M. M. ;

Sadykov, V. A. ;

Sadovskaya, E. M. ;

Pelipenko, V. V. ;

Eremeev, N. F. .

SOLID STATE IONICS, 2017, 302 :118-125

[13]

Muzykantov V. S., 1964, KINET KATAL, V4, P624

[14]

PETUSHKOVA LV, 1974, DOKL AKAD NAUK SSSR+, V216, P544

[15] Chemistry, structure and properties of bismuth copper titanate pyrochlores [J].

Piir, I. V. ;

Koroleva, M. S. ;

Ryabkov, Yu. I. ;

Pikalova, E. Yu. ;

Nekipelov, S. V. ;

Sivkov, V. N. ;

Vyalikh, D. V. .

SOLID STATE IONICS, 2014, 262 :630-635

[16] Bismuth iron titanate pyrochlores: Thermostability, structure and properties [J].

Piir, I. V. ;

Koroleva, M. S. ;

Ryabkov, Yu. I. ;

Korolev, D. A. ;

Chezhina, N. V. ;

Semenov, V. G. ;

Panchuk, V. V. .

JOURNAL OF SOLID STATE CHEMISTRY, 2013, 204 :245-250

[17] Bismuth manganese titanate: Crystal structure and properties [J].

Piir, I. V. ;

Sekushin, N. A. ;

Grass, V. E. ;

Ryabkov, Y. I. ;

Chezhina, N. V. ;

Nekipelov, S. V. ;

Sivkov, V. N. ;

Vyalikh, D. V. .

SOLID STATE IONICS, 2012, 225 :464-470

[18] Oxygen migration in A2B2O7 pyrochlores [J].

Pirzada, M ;

Grimes, RW ;

Minervini, L ;

Maguire, JF ;

Sickafus, KE .

SOLID STATE IONICS, 2001, 140 (3-4) :201-208

[19]

Piskaikina M.M., 2015, ACAD SCI, V1, P22

[20] Synthesis and structure of pyrochlore-type bismuth titanate [J].

Radosavljevic, I ;

Evans, JSO ;

Sleight, AW .

JOURNAL OF SOLID STATE CHEMISTRY, 1998, 136 (01) :63-66

← 1 2 3 4 →