Self-assembly synthesis and structure of mono- and di-nuclear uranyl complex

被引:3
作者
Lu, SM
Ke, YX
Li, JM [1 ]
Zhou, SX
Wu, XT
Du, WX
机构
[1] Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Anhui, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
关键词
crystal; structure; dinuclear complex; uranyl compound; two dimension; supramolecular;
D O I
10.1002/crat.200310128
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Mixing the malonate (mal), 4,4'-bipyridine, UO2(CH3COO)(2)(.)2H(2)O in different solvent condition gets two compounds (bpy)(2)(H(2)bpy)[UO2(mal)(2)(mu-H2O)](.)8H(2)O (1) and (H(2)bpy)[UO2(mal)(2)](.)2H(2)O (2). Both complexes contain seven-coordinated pentagonal bipyramidal uranium center. Crystal 1 is mononuclear structure and crystal 2 contains dinuclear [(UO2)(2) (mal)(2)(mu(2)-mal)(2)](4-) subunit. Particularly, Crystal 2 forms the two-dimensional supramolecular topology by hydrogen bonds. The sheet constructs from two sorts of chamber, of which the larger one has two water molecular guests. (C) 2003 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1004 / 1008
页数:5
相关论文
共 50 条
[41]   Inverse design of triblock Janus spheres for self-assembly of complex structures in the crystallization slot via digital alchemy [J].
Rivera-Rivera, Luis Y. ;
Moore, Timothy C. ;
Glotzer, Sharon C. .
SOFT MATTER, 2023, 19 (15) :2726-2736
[42]   Self-assembly synthesis of precursors to potential open framework alkali earth metal-organic complexes [J].
Hamdy, Louise B. ;
Raithby, Paul R. ;
Thomas, Lynne H. ;
Wilson, Chick C. .
NEW JOURNAL OF CHEMISTRY, 2014, 38 (05) :2135-2143
[43]   Synthesis of Adhesive Polyrotaxanes Through Sequential Self-Assembly via Supramolecular Interactions and Dynamic Covalent Interactions [J].
Zhou, Xiaohe ;
Hu, Ziqing ;
Ji, Xiaofan .
CHEMISTRY-A EUROPEAN JOURNAL, 2024, 30 (61)
[44]   Porous graphitic carbon nitride with lamellar structure: Facile synthesis via in-site supramolecular self-assembly in alkaline solutions and superior photocatalytic activity [J].
Zhang, Ling-Xi ;
Huang, Wei-Qing ;
Li, Yuan-Yuan ;
Huang, Gui-Fang .
ADVANCED POWDER TECHNOLOGY, 2019, 30 (01) :120-125
[45]   Synthesis, characterization and molecular structure of 1,1′ bis(diphenylphosphino ferrocene)dioxide complex of uranyl nitrate [J].
Kannan, Shanmugaperumal ;
Deb, Sadhan B. ;
Drew, Michael G. B. .
INORGANICA CHIMICA ACTA, 2010, 363 (10) :2338-2340
[46]   Synthesis and redox-responsive self-assembly of ferrocene grafted Anderson-type polyoxometalate hybrid complexes [J].
Yan, Yi ;
Li, Bao ;
He, Qingyi ;
He, Zhenfeng ;
Ai, Hui ;
Wang, Huanbing ;
Yin, Zhendong ;
Wu, Lixin .
SOFT MATTER, 2012, 8 (05) :1593-1600
[47]   Synthesis, Properties, and Mechanistic Insight into the Self-Assembly of a Lamellar Fibrous Superstructure from a Synthetically Simple Discotic Molecule [J].
Danumah, Christophe ;
Beingessner, Rachel L. ;
Haque, Azizul ;
Ban, Fuqiang ;
Richards, Jeremy P. ;
Kovalenko, Andriy ;
Fenniri, Hicham .
LANGMUIR, 2009, 25 (19) :11857-11861
[48]   Synthesis and comparative structural study of 2-(pyridin-2-yl)-1H-perimidine and its mono- and di-N-methylated analogues [J].
Kalle, Paulina ;
Tatarin, Sergei, V ;
Zakharov, Alexander Yu ;
Kiseleva, Marina A. ;
Bezzubov, Stanislav, I .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2021, 77 :96-+
[49]   Self-assembly hydrogen-bonded supramolecular arrays from copper(II) halogenobenzoates with nicotinamide: Structure and EPR spectra [J].
Halaska, Jozef ;
Cechova, Danica ;
Lawson, Michael K. ;
Ruzickova, Zdenka ;
Jorik, Vladimir ;
Koman, Marian ;
Valko, Marian ;
Kozlevcar, Bojan ;
Moncol, Jan .
CHEMICAL PAPERS, 2016, 70 (01) :101-113
[50]   Bis(dicyclohexylselenophosphinyl)selenide, [Cy2P(Se)]2Se: Synthesis, molecular structure and application for self-assembly of a tetrahedral Cu(I) cluster [J].
Artem'ev, Alexander V. ;
Doronina, Evgeniya P. ;
Bagryanskaya, Irina Yu ;
Klyba, Lyudmila V. .
JOURNAL OF MOLECULAR STRUCTURE, 2018, 1160 :208-214