Self-assembly synthesis and structure of mono- and di-nuclear uranyl complex

被引：3
作者：
Lu, SM
Ke, YX
Li, JM [1 ]
Zhou, SX
Wu, XT
Du, WX
机构：
[1] Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Anhui, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
CRYSTAL RESEARCH AND TECHNOLOGY | 2003年 / 38卷 / 11期
关键词：
crystal; structure; dinuclear complex; uranyl compound; two dimension; supramolecular;
D O I：
10.1002/crat.200310128
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Mixing the malonate (mal), 4,4'-bipyridine, UO2(CH3COO)(2)(.)2H(2)O in different solvent condition gets two compounds (bpy)(2)(H(2)bpy)[UO2(mal)(2)(mu-H2O)](.)8H(2)O (1) and (H(2)bpy)[UO2(mal)(2)](.)2H(2)O (2). Both complexes contain seven-coordinated pentagonal bipyramidal uranium center. Crystal 1 is mononuclear structure and crystal 2 contains dinuclear [(UO2)(2) (mal)(2)(mu(2)-mal)(2)](4-) subunit. Particularly, Crystal 2 forms the two-dimensional supramolecular topology by hydrogen bonds. The sheet constructs from two sorts of chamber, of which the larger one has two water molecular guests. (C) 2003 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：1004 / 1008
页数：5
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