Synthesis and properties of a Cu4(SCN)4 cubane cluster-based coordination polymer with a diamond net

被引：8

作者：

Ren, Shi-Bin ^{[1
,2
]}

Zhou, Le ^{[1
]}

Zhang, Jun ^{[1
]}

Li, Cheng-Hui ^{[1
]}

Li, Yi-Zhi ^{[1
]}

Du, Hong-Bin ^{[1
]}

You, Xiao-Zeng ^{[1
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Taizhou Univ, Sch Pharmaceut & Chem Engn, Taizhou 317000, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 04期

基金：

中国国家自然科学基金;

关键词：

Coordination polymer; CuSCN; Cubane cluster; Diamond net; Photoluminescence; TO-CRYSTAL TRANSFORMATION; PHOTOLUMINESCENCE; SOLIDS; FRAMEWORKS; COMPLEXES; ISOMERISM; ADDUCTS; COPPER; BR; CL;

D O I：

10.1016/j.inoche.2011.01.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A triply-interpenetrating diamondoid coordination polymer [Cu-4(SCN)(4)(tpom)]center dot 2H(2)O (1, tpom = tetrakis (4-pyridyloxymethylene)methane) was prepared, which is built from an unprecedented pseudohalide cubane cluster Cu-4(SCN)(4) and tetrahedral tpom ligand. 1 exhibits high thermal stability and temperature-dependent photoluminescence behaviors resembling those of Cu4Cl4 complexes. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：558 / 561

页数：4

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