Highly sensitive and selective fluorescent sensor for Zn2+/Cu2+ and new approach for sensing Cu2+ by central metal displacement

被引:149
作者
Li, Zhanxian [1 ]
Zhang, Lifeng [1 ]
Wang, Lina [1 ]
Guo, Yongkai [1 ]
Cai, Lianheng [1 ]
Yu, Mingming [1 ]
Wei, Liuhe [1 ]
机构
[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
关键词
LIVING CELLS; EXCIMER FORMATION; ZINC IONS; WATER; CHEMODOSIMETER; CHEMOSENSORS; DESIGN; ROUTE; ZN2+;
D O I
10.1039/c1cc10696a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An "off-on'' Zn2+ and "on-off'' Cu2+ fluorescent chemosensor C was designed and synthesized. The binding of C and Zn2+/Cu2+ is chemically reversible by the addition of EDTA disodium solution; moreover, the fluorescence emission signal of ZnC decreased with the addition of Cu2+, demonstrating that ZnC could detect Cu2+ via metal displacement.
引用
收藏
页码:5798 / 5800
页数:3
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