Electrochemical oxygenation of sulfides with molecular oxygen or water: switchable preparation of sulfoxides and sulfones

被引：14
作者：
Xue, Qi [1 ]
Sun, Qing [1 ]
Zhang, Ting-Ting [1 ]
Li, Yang [1 ]
Li, Jin-Heng [1 ,2 ,3 ]
机构：
[1] Nanchang Hangkong Univ, Key Lab Jiangxi Prov Persistent Pollutants Contro, Nanchang 330063, Jiangxi, Peoples R China
[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
[3] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2021年 / 19卷 / 47期
基金：
中国国家自然科学基金;
关键词：
SULFUR-DIOXIDE; SELECTIVE OXIDATION; PROMOTED OXIDATION; CATALYST; ARYL; CONSTRUCTION; SULFONAMIDES; THIOLS;
D O I：
10.1039/d1ob01756j
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A practical and eco-friendly method for the controllable aerobic oxygenation of sulfides by electrochemical catalysis was developed. The switchable preparation of sulfoxides and sulfones was effectively controlled by reaction time, in which both molecular oxygen and water can be used as the oxygen source under catalyst and external oxidant-free conditions. The electrochemical protocol features a broad substrate scope and excellent site selectivity and is successfully applied to the modification of some sulfide-containing pharmaceuticals and their derivatives.
引用
收藏
页码：10314 / 10318
页数：5
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