Flexible synthesis of high-performance electrode materials of N-doped carbon coating MnO nanowires for supercapacitors

被引:2
作者
Zhou, Ting [1 ]
Zhang, Wenjun [1 ]
Fu, Hao [1 ]
Fang, Jingyuan [1 ]
Chen, Chunnian [1 ]
Wang, Zhongbing [2 ]
机构
[1] Hefei Univ Technol, Sch Chem & Chem Engn, Hefei 230009, Anhui, Peoples R China
[2] Hefei Univ Technol, Instrumental Anal Ctr, Hefei 230009, Anhui, Peoples R China
关键词
MnO; C nanowires; Mn3O4; supercapacitor; GRAPHENE OXIDE COMPOSITE; HYDROTHERMAL SYNTHESIS; MN3O4; NANOPARTICLES; ZNO ELECTRODES; ENERGY; NANOSTRUCTURES; NANOSHEETS; NANOCOMPOSITES; NANOFIBER; NANORODS;
D O I
10.1088/1361-6528/ac394b
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The MnO/C composites were obtained by co-precipitation method, which used Mn3O4 nanomaterials as precursors and dopamine solution after ultrasonic mixing and calcination under N-2 atmosphere at different temperatures. By studying the difference of MnO/C nanomaterials formed at different temperatures, it was found that with the increase of calcination temperature, the materials appear obvious agglomeration. The optimal calcination temperature is 400 degrees C, and the resulting MnO/C is a uniformly dispersed slender nanowire structure. The specific capacitance of MnO/C nanowires can reach 356 F g(-1) at 1 A g(-1). In the meantime, the initial capacitance of MnO/C nanowires remains 106% after 5000 cycles. Moreover, the asymmetric supercapacitor was installed, which displays a tremendous energy density of 30.944 Wh kg(-1) along with a high power density of 10 kW kg(-1). The composite material reveals a promising prospect in the application of supercapacitors.
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页数:11
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共 67 条
[21]   A Facile and Template-Free Hydrothermal Synthesis of Mn3O4 Nanorods on Graphene Sheets for Supercapacitor Electrodes with Long Cycle Stability [J].
Lee, Jeong Woo ;
Hall, Anthony S. ;
Kim, Jong-Duk ;
Mallouk, Thomas E. .
CHEMISTRY OF MATERIALS, 2012, 24 (06) :1158-1164
[22]   Facile synthesis of pseudocapacitive Mn3O4 nanoparticles for high-performance supercapacitor [J].
Li, Bin ;
Zhang, Xihua ;
Dou, Jinhe ;
Hu, Cheng .
CERAMICS INTERNATIONAL, 2019, 45 (13) :16297-16304
[23]   CoS2 nanodots anchored into heteroatom-doped carbon layer via a biomimetic strategy: Boosting the oxygen evolution and supercapacitor performance [J].
Li, Bingyue ;
Xing, Ruimin ;
Mohite, Santosh V. ;
Latthe, Sanjay S. ;
Fujishima, Akira ;
Liu, Shanhu ;
Zhou, Yanmei .
JOURNAL OF POWER SOURCES, 2019, 436
[24]   Polydopamine directed MnO@C microstructures as electrode for lithium ion battery [J].
Li, Delu ;
Zhang, Yejun ;
Li, Lun ;
Hu, Feng ;
Yang, Hongchao ;
Wang, Changhong ;
Wang, Qiangbin .
SCIENCE CHINA-CHEMISTRY, 2016, 59 (01) :122-127
[25]   Hydrothermal synthesis of mesoporous MnCo2O4/CoCo2O4 ellipsoid-like microstructures for high-performance electrochemical supercapacitors [J].
Liao, Fan ;
Han, Xingrong ;
Zhang, Yanfei ;
Han, Xinghua ;
Xu, Chunju ;
Chen, Huiyu .
CERAMICS INTERNATIONAL, 2019, 45 (06) :7244-7252
[26]   Ultrathin MnO2 nanosheets grown on hollow carbon spheres with enhanced capacitive performance [J].
Liu, Jinghua ;
Li, Fengfan ;
Li, Xin ;
He, Xiong .
PHYSICS LETTERS A, 2020, 384 (22)
[27]   Core-Shell Nitrogen-Doped Carbon Hollow Spheres/Co3O4 Nanosheets as Advanced Electrode for High-Performance Supercapacitor [J].
Liu, Tao ;
Zhang, Liuyang ;
You, Wei ;
Yu, Jiaguo .
SMALL, 2018, 14 (12)
[28]   Hierarchical SnO2 Nanostructures Made of Intermingled Ultrathin Nanosheets for Environmental Remediation, Smart Gas Sensor, and Supercapacitor Applications [J].
Liu, Yang ;
Jiao, Yang ;
Zhang, Zhenglin ;
Qu, Fengyu ;
Umar, Ahmad ;
Wu, Xiang .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (03) :2174-2184
[29]   Flexible Supercapacitor Electrodes Based on Carbon Cloth-Supported LaMnO3/MnO Nano-Arrays by One-Step Electrodeposition [J].
Ma, Pianpian ;
Lei, Na ;
Yu, Bo ;
Liu, Yongkun ;
Jiang, Guohua ;
Dai, Jianming ;
Li, Shuhong ;
Lu, Qiuling .
NANOMATERIALS, 2019, 9 (12)
[30]   Synthesis of Co-based Prussian Blue Analogues/Dual-Doped Hollow Carbon Microsphere Hybrids as High-Performance Bifunctional Electrocatalysts for Oxygen Evolution and Overall Water Splitting [J].
Ma, Xiao ;
Chang, Chengshuai ;
Zhang, Yunqiang ;
Niu, Ping ;
Liu, Xuan ;
Wang, Shulan ;
Li, Li .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (22) :8318-8326