Subsolidus phase diagrams of the systems Cs2MoO4-R2(MoO4)3-Zr(MoO4)2, where r = al, sc, or in

被引:5
作者
Bazarov, B. G. [1 ]
Namsaraeva, T. V.
Fedorov, K. N.
Bazarova, Zh. G.
机构
[1] Russian Acad Sci, Siberian Div, Baikal Inst Nat Management, Ulan Ude, Buryat Republ, Russia
[2] Buryat State Univ, Ulan Ude, Buryat Republ, Russia
基金
俄罗斯基础研究基金会;
关键词
Molybdate; Scandium; Component Ratio; Buryat Republic; Subsolidus Region;
D O I
10.1134/S0036023607090240
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The systems Cs2MoO4-R-2(MoO4)(3)-Zr(MoO4)(2), where R = Al, Sc, or In, have been investigated in the subsolidus region by X-ray powder diffraction. Quasi-binary joins have been revealed, and triangulation has been carried out. Six new triple molybdates have been prepared with the component ratio equal to 1 : 1 : 1 (mol/mol) (S-1) and 5 : 1 : 2 (S-2). The crystal parameters for the 5 : 1 : 2 compounds have been determined, and the electrical properties of the 1 : 1 : 1 compounds have been investigated.
引用
收藏
页码:1454 / 1458
页数:5
相关论文
共 7 条
[1]  
BAZAROV BG, 2004, ZH STRUKT KHIM, V45, P1038
[2]   REVISED EFFECTIVE IONIC-RADII AND SYSTEMATIC STUDIES OF INTERATOMIC DISTANCES IN HALIDES AND CHALCOGENIDES [J].
SHANNON, RD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (SEP1) :751-767
[3]  
TRUNOV VK, 1986, CRYSTAL CHEM DOUBLAE
[4]  
TSYBULYA SV, 1996, ZH STRUKT KHIM, V37, P379
[5]  
TUSHINOVA YL, 2002, P ALL RUSS READ FOR, P90
[6]  
VELIKODNYI YA, 1975, THESIS MOSCOW
[7]  
ZOLOTOVA ES, 1986, THESIS NOVOSIBIRSK