Poly(Acrylonitrile-Butadiene-Styrene) as a Special β-Nucleating Agent on the Toughness of Isotactic Polypropylene

The influence of poly(acrylonitrile-butadiene-styrene) (ABS) as a special beta-nucleating agent on the impact and tensile properties of isotactic polypropylene (iPP) were investigated by dynamic rheological measurements, wide-angle X-ray diffraction (WAXD), differential scanning calorimetry (DSC), scanning electron microscopy (SEM), and mechanical properties tests. It is found that the beta nucleation efficiency of ABS is closely related to its concentration, dispersibility, and molding method for the iPP/ABS blends. The content of beta-crystal (K-beta) rises with the incorporation of ABS and shows a maximum with the introduction of 1% ABS for compression-molded blends and 2% ABS for injection-molded blends, respectively, which is followed by a decrease in K-beta. The addition of a small amount of ABS has a significant reinforcing and toughening effect on iPP. Compared with the compression-molded samples, the ABS dispersed phase in injection-molded samples has a smaller particle size and a larger specific surface area, which are favorable for stress transmission and higher beta nucleation efficiency, and therefore, better tensile and impact properties can be expected.