Basic zeolite and zeolite-type catalysts for the oxidative methylation of toluene with methane

被引：22

作者：

Kovacheva, P ^{[1
]}

Arishtirova, K ^{[1
]}

Predoeva, A ^{[1
]}

机构：

[1] Bulgarian Acad Sci, Inst Catalysis, BU-1113 Sofia, Bulgaria

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 2003年 / 79卷 / 01期

关键词：

basic zeolite and zeolite-type catalysts; oxidative methylation of toluene; methane; TPD of CO2;

D O I：

10.1023/A:1024176121544

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidative methylation of toluene with methane is used as a test reaction for determining the activity, selectivity and yield of C-8 hydrocarbons (ethylbenzene and styrene) over different zeolite and zeolite-type catalysts, viz., X, Y, mordenite, ZSM-5, silicalite and AlPO4-5. Selectivity and basicity increase with decreasing Si/Al atomic ratio within the series of the same structural type. The basicity, surface structure and structural integrity are characterized by TPD of CO2, XPS and IRS, respectively.

引用

页码：149 / 155

页数：7

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