A high-rate manganese oxide for rechargeable lithium battery applications

被引：67

作者：

Doeff, MM ^{[1
]}

Anapolsky, A

Edman, L

Richardson, TJ

De Jonghe, LC

机构：

[1] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Sci Mat, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Environm Energy Technol Div, Berkeley, CA 94720 USA

[3] Umea Univ, Dept Expt Phys, S-90187 Umea, Sweden

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2001年 / 148卷 / 03期

关键词：

D O I：

10.1149/1.1349883

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

LixMnO2 made by ion exchange of glycine-nitrate combustion synthesis-processed (GNP) orthorhombic Na0.44MnO2 (GNP-LixMnO2) has been cycled in lithium/liquid electrolyte cell configurations at room temperature and lithium/polymer cell configurations at 85 degreesC over one hundred times without showing capacity fading or phase conversion to spinel. At 2.5 mA/cm(2) in liquid cells (5C rate) or 1 mA/cm(2) (1.5C rate) in polymer cells, 80-95% of the expected capacity is delivered. The remarkable stability is attributable to the unusual double tunnel structure, which cannot easily undergo rearrangement to spinel. The enhanced rats capability of GNP-LixMnO2 compared to conventionally prepared materials is attributable to the shorter particle length, which allows faster diffusion of lithium ions along the tunnels. (C) 2001 The Electrochemical Society. All rights reserved.

引用

页码：A230 / A236

页数：7

共 23 条

[1]

ANAPOLSKY A, 2000, THESIS U CALIFORNIA

[2]

[Anonymous], UNPUB

[3] Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteries [J].

Armstrong, AR ;

Bruce, PG .

NATURE, 1996, 381 (6582) :499-500

[4] Li0.44MnO2:: an intercalation electrode with a tunnel structure and excellent cyclability [J].

Armstrong, AR ;

Huang, H ;

Jennings, RA ;

Bruce, PG .

JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (01) :255-259

[5] Self-discharge of LiMn2O4/C Li-ion cells in their discharged state -: Understanding by means of three-electrode measurements [J].

Blyr, A ;

Sigala, C ;

Amatucci, G ;

Guyomard, D ;

Chabre, Y ;

Tarascon, JM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (01) :194-209

[6] GLYCINE NITRATE COMBUSTION SYNTHESIS OF OXIDE CERAMIC POWDERS [J].

CHICK, LA ;

PEDERSON, LR ;

MAUPIN, GD ;

BATES, JL ;

THOMAS, LE ;

EXARHOS, GJ .

MATERIALS LETTERS, 1990, 10 (1-2) :6-12

[7]

Cho J, 1999, J ELECTROCHEM SOC, V146, P3577, DOI 10.1149/1.1392517

[8] ORTHORHOMBIC NAXMNO2 AS A CATHODE MATERIAL FOR SECONDARY SODIUM AND LITHIUM POLYMER BATTERIES [J].

DOEFF, MM ;

PENG, MY ;

MA, YP ;

DEJONGHE, LC .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (11) :L145-L147

[9] Lithium insertion processes of orthorhombic NaxMnO2-based electrode materials [J].

Doeff, MM ;

Richardson, TJ ;

Kepley, L .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (08) :2507-2516

[10]

Doeff MM, 1995, MATER RES SOC SYMP P, V393, P107, DOI 10.1557/PROC-393-107

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