Hydrothermal fabrication and characterization of novel CeO2/PbWO4 nanocomposite for enhanced visible-light photocatalytic performance

被引:26
作者
Selvi, S. [1 ]
Rajendran, Ranjith [2 ]
Jayamani, N. [1 ]
机构
[1] Govt Arts Coll Autonomous, Dept Phys, Salem 636001, Tamil Nadu, India
[2] Periyar Univ, Dept Phys, Salem 636011, Tamil Nadu, India
关键词
CeO2/PbWO4; Nanocomposites; Hydrothermal; Visible light; Photodegradation; Active species;
D O I
10.1007/s13201-021-01429-x
中图分类号
TV21 [水资源调查与水利规划];
学科分类号
081501 ;
摘要
In this revision, a series of novel visible-light-driven (VLD) CeO2/PbWO4 nanocomposites (NCs) were effectively fabricated by facile hydrothermal preparation way. The UV-Vis absorption spectra exposed that CeO2 NPs prolonged the adsorption edge of the CeO2/PbWO4 composite to the extensive visible region, which allied to decreases of the bandgap. As-prepared CeO2/PbWO4 NCs revealed superior photocatalytic action under visible-light and could degrade the Methylene Blue (MB) dye solution in 140 min. The photodegradation efficacy of CeO2/PbWO4 NCs was improved catalytic activity, which is around 1.45 and 2.7 times that of CeO2 and PbWO4 nanoparticles (NPs) individually. Besides, the CeO2/PbWO4 catalysts display notable stability and reusability performance in four succeeding cycles. The development in the photocatalytic enactment of combined CeO2/PbWO4 nanocomposite could be recognized not only to the sturdy visible-light absorption responses and separating the photoexcited electron-hole pairs. Also, the plausibly systematic illumination of charge transference and exploitation of reactive species for superior photocatalytic action in visible-light have been discussed. It is projected that the CeO2/PbWO4 NCs could be used as effective photocatalysts for promising applications for environmental wastewater refinement.
引用
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页数:14
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