Recognition of Chiral Carboxylic Anions by Artificial Receptors

被引：29

作者：

Dieng, Pape Sylla ^{[1
]}

Sirlin, Claude ^{[1
]}

机构：

[1] Univ Strasbourg, Inst Chim CNRS UMR7177, F-67070 Strasbourg, France

来源：

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES | 2010年 / 11卷 / 09期

关键词：

molecular recognition; anion recognition; chiral carboxylic anions recognition; HIGHLY ENANTIOSELECTIVE RECOGNITION; ALPHA-AMINO-ACIDS; MOLECULAR RECOGNITION; CRYSTAL-STRUCTURE; POLYAMMONIUM MACROCYCLES; BINDING PROPERTIES; COORDINATION; VANCOMYCIN; LIGANDS; COMPLEXES;

D O I：

10.3390/ijms11093334

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Many carboxylic molecules, ranging from drugs to flavors and fragrances, contain chiral centers. As a consequence, research has been carried out in order to design and synthesize artificial receptors for carboxylic anions. Many problems have to be solved for binding anions. The results obtained in the binding of carboxylic anions by guanidine, secondary ammonium and metal-center have been selected. The last part of this review focuses on chiral recognition of carboxylic anions by organic and metal-based chiral receptors.

引用

页码：3334 / 3348

页数：15

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